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An efficient synthesis of quinazoline and xanthene derivatives using starch sulfate as a biodegradable solid acid catalyst

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Abstract

Starch sulfate as bio-supported solid acid catalyst was applied to synthesis of heterocyclic compounds such as 2,3-dihydroquinazolin-4(1H)-one, 2-substituted-1,2,3,4-tetrahydro-4-quinazolinones, 12-aryl-8,9,10,12-tetrahydrobenzo[a]xanthen-11-one, 1,8-dioxo-octahydroxanthenes, and 5H-dibenzo[b,i]xanthene-5,7,12,14(13H)-tetraone derivatives under thermal solvent-free conditions. In all these synthetic methods, the work-up is simple and the catalyst can be easily separated from the product and reused for several times without any loss of its activity. The present protocol with starch sulfate as an effective catalyst is convincingly superior to the recently reported catalytic methods with respect to reaction times and yields of the obtained products.

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Acknowledgment

We are grateful to the University of Sistan and Baluchestan Research Council for the partial support of this research.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Sciences, University of Sistan and Baluchestan, PO Box 98135-674, Zahedan, Iran

    Hamid Reza Shaterian & Fatemeh Rigi

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  1. Hamid Reza Shaterian
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  2. Fatemeh Rigi
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Correspondence to Hamid Reza Shaterian.

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Shaterian, H.R., Rigi, F. An efficient synthesis of quinazoline and xanthene derivatives using starch sulfate as a biodegradable solid acid catalyst. Res Chem Intermed 41, 721–738 (2015). https://doi.org/10.1007/s11164-013-1223-z

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  • DOI: https://doi.org/10.1007/s11164-013-1223-z

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