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Synthesis, characterization, and application of poly(4-vinylpyridinium butane sulfonic acid) hydrogen sulfate as a novel poly(ionic liquid) and heterogeneous solid acid catalyst for the preparation of 1,8-dioxo-octahydroxanthenes

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Abstract

Poly(4-vinylpyridinium butane sulfonic acid) hydrogen sulfate, P(4VPBSA)HSO4, a novel polymeric acidic catalyst, was easily prepared by reaction of cross-linked poly(4-vinylpyridine) with 1,4-butane sultone and further acidification of the catalyst with sulfuric acid. The catalyst was studied by FT-IR spectroscopy, scanning electron microscopy, and thermogravimetric analysis. The poly(ionic liquid) catalyst was shown to be an efficient dual acidic catalyst for one-pot preparation of 1,8-dioxo-octahydroxanthenes under solvent-free conditions. Reusability of the catalyst, easy work-up, eco-friendly reaction conditions, short reaction times, and high yields are some advantages of this procedure.

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Acknowledgments

We gratefully acknowledge support of this work by Shahid Chamran University Research Council. We are grateful to M. R. Fazeli-Mobarakeh for recording SEM images.

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Authors and Affiliations

  1. Chemistry Department, College of Science, Shahid Chamran University, P. O. Box 61357-4-3169, Ahvaz, Iran

    Ali Reza Kiasat, Arash Mouradzadegun & Seyyed Jafar Saghanezhad

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  1. Ali Reza Kiasat
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  2. Arash Mouradzadegun
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  3. Seyyed Jafar Saghanezhad
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Correspondence to Ali Reza Kiasat.

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Kiasat, A.R., Mouradzadegun, A. & Saghanezhad, S.J. Synthesis, characterization, and application of poly(4-vinylpyridinium butane sulfonic acid) hydrogen sulfate as a novel poly(ionic liquid) and heterogeneous solid acid catalyst for the preparation of 1,8-dioxo-octahydroxanthenes. Res Chem Intermed 41, 319–326 (2015). https://doi.org/10.1007/s11164-013-1194-0

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