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Nanocrystalline 5 % Fe/ZnO as an efficient catalyst for quinoxaline synthesis

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Abstract

Various 2-aryl quanoxalines were synthesized with good yields from o-phenylene diamines and phenacyl bromides in one pot using novel nanocrystalline 5 % Fe/ZnO catalyst, at room temperature. The salient feature of this method includes mild reaction conditions, short reaction time, good yield, high purity of product, and recyclable catalyst without noticeable decrease in catalytic activity, which can be used for large-scale synthesis. The synthesized 5 % Fe/ZnO nanoparticles were characterized by using XRD, SEM, and TEM techniques.

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Acknowledgments

Authors are grateful to UGC New Delhi for financial support, and also grateful to University of Pune and IIT Mumbai for providing 1H and 13C NMR analysis.

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Authors and Affiliations

  1. Research Centre, Department of Chemistry, HPT Arts and RYK Science College, Nasik, 422005, India

    Ashok V. Borhade, Dipak R. Tope & Dattaprasad R. Patil

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  1. Ashok V. Borhade
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  2. Dipak R. Tope
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  3. Dattaprasad R. Patil
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Correspondence to Ashok V. Borhade.

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Borhade, A.V., Tope, D.R. & Patil, D.R. Nanocrystalline 5 % Fe/ZnO as an efficient catalyst for quinoxaline synthesis. Res Chem Intermed 39, 1373–1383 (2013). https://doi.org/10.1007/s11164-012-0693-8

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  • DOI: https://doi.org/10.1007/s11164-012-0693-8

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