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Synthesis and characterization of binuclear Zn(II)–cyclen complexes bridged by α,ω-bis(4-methylphenoxy) alkanes

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Abstract

A series of novel α,ω-bis(4-methylphenoxy) alkane functionalized cyclen ligands were synthesized by the nucleophilic substitution reaction of 1,4,7-tris(tert-butyloxycarbonyl)-1,4,7,10-tetraazacyclododecane and α,ω-bis(4-bromomethylphenoxy) alkanes. The corresponding dimeric Zn(II)–cyclen complexes were obtained by reaction of these ligands with Zn(ClO4)2·6H2O. Ligands and complexes were characterized by FT-IR, 1H NMR, and elemental analysis.

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Acknowledgments

The authors thank Dr Xiao-hui Xiao (College of Chemistry and Life Science, Zhejiang Normal University, Jinhua Zhengjiang P.R. China) for help with the experiments.

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  1. College of Chemistry and Material Science, Shandong Agricultural University, Taian, 271018, People’s Republic of China

    Fuxian Wan, Changcheng Li, Lin Jiang & Ying Li

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  1. Fuxian Wan
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  2. Changcheng Li
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  3. Lin Jiang
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Correspondence to Fuxian Wan.

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Wan, F., Li, C., Jiang, L. et al. Synthesis and characterization of binuclear Zn(II)–cyclen complexes bridged by α,ω-bis(4-methylphenoxy) alkanes. Res Chem Intermed 38, 2085–2096 (2012). https://doi.org/10.1007/s11164-012-0528-7

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  • DOI: https://doi.org/10.1007/s11164-012-0528-7

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