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Absorption, fluorescence, and photoinitiating properties of the aromatic ethers and aromatic amines complexes of cyclopentadienyliron

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Abstract

The aromatic ethers complexes of cyclopentadienyliron (O-CpFe) and aromatic amines complexes of cyclopentadienyliron (N-CpFe) were prepared by coupling several aniline derivatives and phenol derivatives with (η6-chlorobenzene) (η5-cyclopentadienyl) iron hexafluorophosphate through nucleophilic aromatic substitution reaction. The UV/vis absorption, fluorescence, and excitation spectra of the compounds were measured. The abilities of the photoinitiator in photopolymerizing the diglycidyl ether of the bisphenol-A epoxy oligomer under a halogen lamp were evaluated by near-infrared spectroscopy. The results show that the absorption of N-CpFe is higher than that of O-CpFe in the visible region. However, the photoinitiation ability of N-CpFe is lower than that of O-CpFe.

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Acknowledgments

The authors are thankful for the financial support provided by the National Natural Science Foundation of China (Project Grant no. 20676012).

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Authors and Affiliations

  1. Department of Organic Chemistry, College of Science, Beijing University of Chemical Technology 144#, Beijing, 100029, People’s Republic of China

    Guang-Lei Li, Guo-cheng Zhang, Yu Chen & Tao Wang

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  1. Guang-Lei Li
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  2. Guo-cheng Zhang
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  3. Yu Chen
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  4. Tao Wang
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Correspondence to Tao Wang.

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Li, GL., Zhang, Gc., Chen, Y. et al. Absorption, fluorescence, and photoinitiating properties of the aromatic ethers and aromatic amines complexes of cyclopentadienyliron. Res Chem Intermed 37, 847–857 (2011). https://doi.org/10.1007/s11164-011-0292-0

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