Skip to main content
SpringerLink
Log in

Controlled synthesis of tetragonal terbium orthophosphate nanostructures through a solvothermal route

  • Published:
Research on Chemical Intermediates Aims and scope Submit manuscript

Abstract

The tetragonal TbPO4 was controlled synthesized via a simple solvothermal route by using glycol as solvent. The structures and micromorphologies of the as-synthesized TbPO4 have been investigated by means of X-ray powder diffraction (XRD) and field-emission scanning electronic microscopy (FE-SEM). The results showed that the tetragonal TbPO4 are composed of square-like particles about 200 nm in diameter. The photoluminescence spectra exhibited that the emission spectra of the sample could be divided into two parts, representing the 5D4 → 7FJ (J = 6, 5, 4, 3) transitions and 5D3 → 7FJ (J = 6, 5, 4, 3) transitions of Tb3+.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5

Similar content being viewed by others

References

  1. G.Y. Adachi, N. Imanaka, Chem. Rev. 98, 1479 (1998)

    Article  CAS  Google Scholar 

  2. R.X. Yan, X.M. Sun, X. Wang, Q. Peng, Y.D. Li, Chem. Eur. J. 11, 2183 (2005)

    Article  CAS  Google Scholar 

  3. S.P. Fricker, Chem. Soc. Rev. 35, 524 (2006)

    Article  CAS  Google Scholar 

  4. J. Dhanaraj, R. Jagannathan, T.R.N. Kutty, C.-H. Lu, J. Phys. Chem. B 105, 11098 (2001)

    Article  CAS  Google Scholar 

  5. H. Mass, A. Currao, G. Calzaferri, Angew. Chem. Int. Ed. 41, 2495 (2002)

    Article  Google Scholar 

  6. F.H. Firsching, S.N. Brune, J. Chem. Eng. Data 36, 93 (1991)

    Article  CAS  Google Scholar 

  7. A. Rouanet, J.J. Serra, K. Allaf, V.P. Orlovskii, Neorg. Mater. 17, 104–109 (1981)

    CAS  Google Scholar 

  8. Y. Guo, P. Woznicki, A. Barkatt, E.E. Saad, I.G. Talmy, J. Mater. Res. 11, 639 (1996)

    Article  CAS  Google Scholar 

  9. O. Lehmann, K. Kompe, M. Haase, J. Am. Chem. Soc. 126, 14935 (2004)

    Article  CAS  Google Scholar 

  10. K. Riwotzki, H. Meyssamy, A. Kornowski, M. Haase, J. Phys. Chem. B 104, 2824 (2000)

    Article  CAS  Google Scholar 

  11. P. Schuetz, F. Caruso, Chem. Mater. 14, 4509 (2002)

    Article  CAS  Google Scholar 

  12. Y.P. Fang, A.W. Xu, R.Q. Song, H.X. Zhang, L.P. You, J.C. Yu, H.Q. Liu, J. Am. Chem. Soc. 125, 16025 (2003)

    Article  CAS  Google Scholar 

  13. Y.W. Zhang, Z.G. Yan, L.P. You, R. Si, C.H. Yan, Eur. J. Inorg. Chem. 22, 4099 (2003)

    Article  Google Scholar 

  14. W.B. Bu, Z.L. Hua, H.R. Chen, J.L. Shi, J. Phys. Chem. B 109, 14461 (2005)

    Article  CAS  Google Scholar 

  15. J. Bao, R. Yu, J. Zhang, D. Wang, J. Deng, J. Chen, X. Xing, Scripta Mater. 62, 133 (2010)

    Article  CAS  Google Scholar 

  16. J. Bao, R. Yu, J. Zhang, X. Yang, D. Wang, J. Deng, J. Chen, X. Xing, Cryst. Eng. Commun. 11, 1630 (2009)

    CAS  Google Scholar 

  17. K. Riwotzki, H. Meyssamy, H. Schnablegger, A. Kornowski, M. Haase, Angew. Chem. Int. Ed. 40, 573 (2001)

    Article  CAS  Google Scholar 

  18. K. Kompe, H. Borchert, J. Storz, A. Lobo, S. Adam, T. Moller, M. Haase, Angew. Chem. Int. Ed. 42, 5513 (2003)

    Article  Google Scholar 

  19. G. Buhler, C. Feldmann, Angew. Chem. Int. Ed. 45, 4864 (2006)

    Article  Google Scholar 

  20. R. Kijkowska, J. Mater. Sci. 38, 229 (2003)

    Article  CAS  Google Scholar 

  21. J.R. Bao, R.B. Yu, J.Y. Zhang, X.D. Yang, D. Wang, J.X. Deng, J. Chen, X.R. Xing, Eur. J. Inorg. Chem. 2388 (2009)

  22. W.H. Di, X.J. Wang, P.P. Zhu, B.J. Chen, J. Solid State Chem. 180, 467 (2007)

    Article  CAS  Google Scholar 

Download references

Acknowledgments

This work was financially supported by the National Natural Science Foundation of China (No. 20871015, 51072020), “Program for New Century Excellent Talents in University” (NCET), Beijing Natural Science Foundation (No. 2092019, 2082022), GF Fundamental Research Foundation (A1320070102), and the National Natural Science Foundation of Inner Mongolia Autonomous Region (No. 09208).

Author information

Authors and Affiliations

  1. Department of Physical Chemistry, University of Science and Technology Beijing, Beijing, 100083, People’s Republic of China

    Ranbo Yu, Jinrong Bao, Xiaodan Yang, Jiayun Zhang, Jinxia Deng, Jun Chen & Xianran Xing

  2. School of Chemistry and Chemical Engineering, University of Inner Mongolia, Hohhot, 010021, People’s Republic of China

    Jinrong Bao

Authors
  1. Ranbo Yu
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Jinrong Bao
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Xiaodan Yang
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Jiayun Zhang
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Jinxia Deng
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Jun Chen
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. Xianran Xing
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Ranbo Yu.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Yu, R., Bao, J., Yang, X. et al. Controlled synthesis of tetragonal terbium orthophosphate nanostructures through a solvothermal route. Res Chem Intermed 37, 145–151 (2011). https://doi.org/10.1007/s11164-011-0261-7

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11164-011-0261-7

Keywords

Search

Navigation