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Study by Mössbauer-Spectroscopy of Iron Oxides in Acid-Resistant Ceramic Materials Based on Production Waste

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Refractories and Industrial Ceramics Aims and scope

The distribution of iron ions during firing of acid-resistant ceramic materials based on production waste is established using the Mössbauer effect. It is revealed that in samples containing an increased amount of iron oxide (17 – 18%) strength and frost resistance are better than in specimens containing 6 – 7 % Fe2O3. Calculation of the areas of the doublets of the spectrum showed that iron compounds at the surface of the samples studied (where an oxidizing atmosphere predominates) are mainly represented by hematite, and in their central part (reducing atmosphere) by magnetite, and in this case specimen acid resistance is reduced.

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Acknowledgement

Work was carried out within the scope of implementing a scientific and technical project approved for a financing grant in 2018 – 2019 by the National Science Council of the Kazakhstan Republic for Science “Rational use of natural resources, including water resources, geology, processing, new materials and technology, safe objects in construction.” Agreement for financial grant No. 177 of 15 March 2018, IRN 05132501.

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Correspondence to A. K. Kairakbaev.

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Translated from Novye Ogneupory, No. 3, pp. 56 – 60, March, 2020.

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Kairakbaev, A.K., Abdrakhimov, V.Z. & Abdrakhimova, E.S. Study by Mössbauer-Spectroscopy of Iron Oxides in Acid-Resistant Ceramic Materials Based on Production Waste. Refract Ind Ceram 61, 183–187 (2020). https://doi.org/10.1007/s11148-020-00452-w

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  • DOI: https://doi.org/10.1007/s11148-020-00452-w

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