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High Density Boron Carbide Ceramics

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Refractories and Industrial Ceramics Aims and scope

Porous preforms of B4C + C and B4C + C + Si materials were impregnated by liquid (molten) silicon to obtain high-density product with a relative density of 99.0 % and porosity of 0.9%. Silicon impregnation was carried out by saturating the samples through the pores of the SiC + C sacrificial preforms. This method allows to reduce both the dissolution of boron carbide grains in the silicon solution and the formation of the B12(C, Si, B)3 phase. This reduces the fragility of the product and thereby improves the mechanical characteristics of the B4C ceramics.

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References

  1. A. K. Suri, C. Subramanian, J. K. Sonber, and T. C. Murthy, “Synthesis and consolidation of boron carbide: a review,” Int. Mater. Rev., 55(1), 4 – 40 (2010).

    Article  Google Scholar 

  2. P. Larsson, N. Axen, and S. Hogmark, “Improvements of the microstructure and erosion resistance of boron carbide with additives,” J. Mater. Sci., 35(14), 3433 – 3440 (2000).

    Article  Google Scholar 

  3. N. Cho, Z. Bao, and R. F. Speyer, “Density- and hardness-optimized pressureless sintered and post-hot isostatic pressed B4C,” J. Mater. Res., 20(8), 2110 – 2116 (2005).

    Article  Google Scholar 

  4. X. Du, Z. Zhang, Y. Wang, et al., “Hot-pressing kinetics and densification mechanisms of boron carbide,” J. Am. Ceram. Soc., 98(5), 1400 – 1406 (2015).

    Article  Google Scholar 

  5. J. H. Chae, J. S. Park, J. P. Ahn, and K. H. Kim, “Mechanical properties of B4C ceramics fabricated by a hot-press sintering,” J. Korean Ceram. Soc., 46(1), 81 – 85 (2009).

    Article  Google Scholar 

  6. H. Lee and R. F. Speyer, “Pressureless sintering of boron carbide,” J. Am. Ceram. Soc., 86(9), 1468 – 1473 (2003).

    Article  Google Scholar 

  7. C. P. Zhang, H. Q. Rue, X. Y. Yue, and W. Wang, “Studies on the RBBC ceramics fabricated by reaction bonded SiC,” Rare Metal Mater. Eng., 40, 536 – 539 (2011).

    Article  Google Scholar 

  8. P. Barick, D. C. Jana, and N. Thiyagarajan, “Effect of particle size on the mechanical properties of reaction bonded boron carbide ceramics,” Ceram. Int., 39(1), 763 – 770 (2013).

    Article  Google Scholar 

  9. C. Zhang, H. Ru, H. Zong, et al., “Coarsening of boron carbide grains during the infiltration of porous boron carbide pre-forms by molten silicon,” Ceram. Int., 42(16), 18681 – 18691 (2016).

    Article  Google Scholar 

  10. N. A. Golubeva, L. A. Plyasunkova, I. Yu. Kelina, et al., “Study of reaction-bonded boron carbide properties,” Refract. Ind. Ceram., 55(5), 414 – 418 (2015).

    Article  Google Scholar 

  11. X. Li, D. Jiang, J. Zhang, et al., “Reaction-bonded B4C with high hardness,” Int. J. Appl. Ceram. Technol., 13(3), 584 – 592 (2016).

    Article  Google Scholar 

  12. Y.Wang, S. Tan, and D. Jiang, “The effect of porous carbon preform and the infiltration process on the properties of reaction-formed SiC,” Carbon, 42(8), 1833 – 1839 (2004).

    Article  Google Scholar 

  13. J. C. Margiotta, D. Zhang, D. C. Nagle, and C. E. Feeser, “Formation of dense silicon carbide by liquid silicon infiltration of carbon with engineered structure,” J. Mater. Res., 23(5), 1237 – 1248.

  14. S. Xu, G. Qiao, D. Li, et al., “Reaction forming of silicon carbide ceramic using phenolic resin derived porous carbon preform,” J. Europ. Ceram. Soc., 29, No. 11, 2395 – 2402 (2009).

    Article  Google Scholar 

  15. D. D. Nesmelov and S. N. Perevislov, “Reaction sintered materials based on boron carbide and silicon carbide,” Glass Ceram., 71(9/10), 313 – 319 (2015).

    Article  Google Scholar 

  16. S. Hayun, A.Weizmann, M. P. Dariel, and N. Frage, “The effect of particle size distribution on the microstructure and the mechanical properties of boron carbide-based reaction-bonded composites,” Int. J. Appl. Ceram. Technol., 6(4), 492 – 500 (2009).

    Article  Google Scholar 

  17. D. Mallick, T. K. Kayal, J. Ghosh, et al., “Development of multi-phase B–Si–C ceramic composite by reaction sintering,” Ceram. Int., 35(4), 1667 – 1669 (2009).

    Article  Google Scholar 

  18. Y.-X.Wang, Sh.-H. Tan, and D.-L. Jiang, “The fabrication of reaction-formed silicon carbide with controlled microstructure by infiltrating a pure carbon preform with molten Si,” Ceram. Int., 30(3), 435 – 439 (2004).

    Article  Google Scholar 

  19. S. Hayun, A. Weizmann, M. P. Dariel, and N. Frage, “Microstructural evolution during the infiltration of boron carbide with molten silicon,” J. Europ. Ceram. Soc., 30(4), 1007 – 1014 (2010).

    Article  Google Scholar 

  20. M. P. Dariel and N. Frage, “Reaction bonded boron carbide: recent developments,” Adv. Appl. Ceram., 111(5/6), 301 – 310 (2012).

    Article  Google Scholar 

  21. S. N. Perevislov, “Mechanism of liquid-phase sintering of silicon carbide and nitride with oxide activating additives,” Glass Ceram., 70(7/8), 265 – 268 (2013).

    Article  Google Scholar 

  22. V. Sirota, O. Lukianova, V. Krasilnikov, et al., “Microstructural and physical properties of magnesium oxide-doped silicon nitride ceramics,” Results in Physics, 6, 82 – 83 (2016).

    Article  Google Scholar 

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The study was carried out with the financial support of the Russian Foundation for Basic Research, project No. 17-03-00863\17.

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Correspondence to S. N. Perevislov.

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Translated from Novye Ogneupory, No. 1, pp. 33 – 37, January 2018.

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Perevislov, S.N., Shcherbak, P.V. & Tomkovich, M.V. High Density Boron Carbide Ceramics. Refract Ind Ceram 59, 32–36 (2018). https://doi.org/10.1007/s11148-018-0178-4

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  • DOI: https://doi.org/10.1007/s11148-018-0178-4

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