A fundamental possibility is demonstrated of using SHS-extrusion and SHS-compression methods, combining combustion and high-temperature deformation, for preparing compact materials and objects of silicide ceramics based on MoSi2. Formability of silicide ceramic by free SHS-compression is studied. The effect of holding time before high-temperature deformation, heating temperature, and metal binder content in an original charge workpiece, on the degree of synthesized material deformation is studied. Specimen macro- and microstructure, prepared by SHS-extrusion is provided, and the effect of high-temperature heating on specific electrical resistance is also studied.
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References
A. G. Merzhanov, Material Combustion Processes and Synthesis, V. T. Telepa and A. V. Khachoyan, editors) [in Russian], ISMAN, Chernogolovka (1998).
Z. I. Zaki, Y. M. Nasser, and Y. M. Ahmed, “Synthesis of dense mullite/MoSi2 composite for high temperature applications,” Int. J. Refractory Metals & Hard Materials, 45, 23 – 30 (2014).
A. A. Sharif, A. Misra, and T. E. Mitchell, “Strength of MoSi2-based crystals at ultrahigh temperature,” Scripta Materialia, 52, 399 – 402 (2005).
P. S. Kislyi, A. Kh. Badyan, V. S. Kindysheva, et al., High-Temperature Nonmetallic Heaters [in Russian], Naukova Dumka, Kiev (1981).
L. G. Tkachev and M. Ya. Pogrebisskii, “Computer design of electric furnace resistance heaters used in metallurgy,” Élektrometallurgiya, No. 9, 42 – 46 (2000).
Yue Chen, T. Hammerschmidt, D. G. Pettifor, et al., “Influence of vibrational entropy on structural stability of Nb–Si and Mo–Si systems at elevated temperatures,” Acta Materialia, 57, 2657 – 2664 (2009).
F. A. Rioult, S. D. Imhoff, R. Sakidja, et al., “Transient oxidation of Mo–Si–B alloys: Effect of the microstructure size scale,” Acta Materialia, 57, 4600 – 4613 (2009).
S. T. Mileiko, “High-temperature metal matrix composites,” J. Appl. Mechan. Techn. Phys., 55(1), 136 – 146.
I. Grammenos and P. Tsakiropoulos, “Study of the role of Hf, Mo and W additions in the microstructure of Nb–20Si silicide based alloys,” Intermetallics, 19, 1612 – 1621 (2011).
A. M. Stolin and P. M. Bazhin, “Manufacture of multipurpose composite and ceramic materials in the combustion regime and high-temperature deformation (SHS Extrusion),” Theoretical Foundations of Chem. Eng., 48(6), 751 – 763 (2014).
S. N. Galyshev, A. M. Stolin, and P. M. Bazhin, “Preparation of intermetallic materials based on nickel aluminide by free SHS-compression,” Inzh. Fiz., No. 9, 25 – 28 (2009).
A. M. Stolin and P. M. Bazhin, “SHS extrusion: an overview,” Int. J. Self-Propagating High-Temperature Synthesis, 23(2), 65 – 73 (2014).
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Translated from Novye Ogneupory, No. 6, pp. 56 – 61, June 2015.
Proceedings of the International Conference of Refractory Workers and Metallurgists (19 – 20 March 2015, Moscow).
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Stolin, A.M., Bazhin, P.M., Mikheev, M.V. et al. Silicide Ceramic Synthesis Based on Molybdenum Disilicide in a Combustion Regime Under High-Temperature Deformation Conditions. Refract Ind Ceram 56, 304–309 (2015). https://doi.org/10.1007/s11148-015-9835-z
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DOI: https://doi.org/10.1007/s11148-015-9835-z