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Titanium Nitride Synthesis in the Presence of Iodine

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Refractories and Industrial Ceramics Aims and scope

A method is proposed for synthesizing titanium nitride by nitriding titanium metal powder with nitrogen in the presence of iodine vapor, and results are given for its application. It is shown that iodine significantly reduces the nitriding reaction activation energy. It is established that TiN forms even at 250°C. It is detected that the size of TiN crystal blocks formed depends on temperature. A nitriding mechanism is proposed.

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Authors and Affiliations

  1. FGBOU VPO St. Petersburg State Technological University, St. Petersburg, Russia

    S. P. Bogdanov

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  1. S. P. Bogdanov
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Correspondence to S. P. Bogdanov.

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Translated from Novye Ogneupory, No. 5, pp. 48 – 51, May 2015.

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Bogdanov, S.P. Titanium Nitride Synthesis in the Presence of Iodine. Refract Ind Ceram 56, 267–270 (2015). https://doi.org/10.1007/s11148-015-9828-y

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  • DOI: https://doi.org/10.1007/s11148-015-9828-y

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