Abstract
Thermodynamic physicochemical modelling and calculation methods are used to study the effect of temperature on phase and chemical transitions in the system MgO-C-Al-Al2OC-Al8B4C7-Al4O4C-Al2O3-Al4C3-H2O-air at 298–2400 K applied to the behavior of carbonized periclase refractories under production and operating conditions. Partial and total pressure, developed by gaseous reaction products of material with an average pore space (CO2, CO, CH4, H2O, H2, etc.) are determined in relation to pressure. The effect of gasification for the carbon component, porosity, original and atmospheric moisture, that is not currently subject to experimental observation, are considered.
Similar content being viewed by others
References
T. Suruga, “Effect of temperature on MgO-C reaction,” Taikabutsu Overseas, 18(4), 5–10 (1998).
S. M. Kim, P. S. Nicholson, and W. K. Lu, “BOF slag-induced formation and destruction of dense MgO layers in carbon-containing magnesites,” Bull. Amer. Ceram. Soc., 57(7), 649–656 (1978).
C. Baundin, C. Alwazes, and R. Emore, “Influence of chemical reactions in magnesia-graphite refractories: 1. Effect of temperature and high temperature,” J. Amer. Ceram. Soc., 82(12), 3529–3539 (1999).
G. B. Sinyarev, N. A. Vatolin, and B. G. Trusov, Use of a Computer for Thermodynamic Calculations of Metallurgical Processes [in Russian], Nauka, Moscow (1982).
E. Hoeffken and H. Giereg, “Einfluss von Antioxidation auf die Eigenschaften der Magnesia-Kohlensteine,” Stahl und Eisen, 104(16), 69–79 (1984).
A. Yamaguchi, “Effect of oxygen and nitrogen partial pressure on stability of metal, carbide, nitride and oxide in carbon containing refractories,” Taikabutsu Overseas, 7(1), 4–13 (1987).
V. N. Sobol’, A. A. Slobodov, V. V. Podluzhnyi, et al., “ZnS-Ag as a chemical system,” Zh. Prikl. Khim., 66(4), 903–906 (1993).
A. A. Slobodov, S. A. Suvorov, A. V. Moggerin, et al., “Influence of antioxidants on physicochemical properties and quality of periclase-carbon refractories — thermodynamic study,” 2nd Internat. Sci. Conf. “Metallurgy of non-ferrous and rare metals,” Krasnorarsk (2003).
S. A. Suvorov, A. A. Slobodov, S. V. Bocharov, et al., “Thermodynamic modelling of the behavior of carbonized periclase refractories,” Novye Ogneupory, No. 3, 27–31 (2003).
S. A. Suvorov, A. A. Slobodov, Mozhzherin, et al., “Effect of parameters of state on phase transitions of carbonized periclase refractories,” Novye Ogneupory, No. 1, 21–30 (2004).
S. A. Suvorov, V. A. Musevich, and F. R. Iksanov, “Modified carbonized periclase refractories, Novye Ogneupory, No. 3, 52–53 (2007).
Author information
Authors and Affiliations
Additional information
__________
Translated from Novye Ogneupory, No. 10, pp. 44–50, October 2007.
Rights and permissions
About this article
Cite this article
Suvorov, S.A., Musevich, V.A., Iksanov, F.R. et al. Effect of parameters of state on phase transitions of carbonized periclase refractories. Refract Ind Ceram 48, 362–367 (2007). https://doi.org/10.1007/s11148-007-0096-3
Received:
Issue Date:
DOI: https://doi.org/10.1007/s11148-007-0096-3