Abstract
Results of a study of the mullitization in stoichiometric pure oxides Al2O3 and SiO2 doped with topaz are reported. A mineralizing topaz-mediated effect is manifested in the activated synthesis of mullite of short prismatic habit involving products of thermal degradation of topaz (mullite and volatile fluorides). The volatile active fluorides enhance structural imperfections in the reactants and promote their high-temperature interaction. Mullite produced by thermal degradation of topaz plays the role of a seeding agent in the solid-state synthesis of mullite from oxides.
Similar content being viewed by others
REFERENCES
A. V. Beznosikova and D. N. Poluboyarinov, “X-ray analysis of synthetic mullite,” in: Trudy NIIstroikeramiki, Issue 13 [in Russian] (1958), pp. 51–62.
E. B. Krol’ and D. N. Poluboyarinov, “A study of sintered mullite ceramics synthesized from commercial-grade chemicals,” in: Trudy NIIstroikeramiki, Issue 24 [in Russian] (1964), pp. 105–127.
P. P. Budnikov and A. M. Ginstling, Reactions in Solid-State Mixtures [in Russian], Gosstroiizdat, Moscow (1971).
P. P. Budnikov, T. I. Keshishyan, and A. V. Volkova, “The effect of dopants on the kinetics of mullitization at low temperatures,” Zh. Prikl. Khim., 36, Issue5, 1064–1068 (1963).
V. S. Bakunov, V. L. Balkevich, et al., Ceramics from High Refractory Oxides [in Russian], Metallurgiya, Moscow (1977).
D. N. Poluboyarinov, V. L. Balkevich, and R. Ya. Popil’skii, High-Alumina Ceramic and Refractory Materials [in Russian], Gosstroiizdat, Moscow (1960).
T. V. Vakalova, V. M. Pogerbenkov, A. V. Ivanchenkov, et al., “Synthesis of mullite from topaz, refractory clays, and clay-topaz compositions,” Novye Ogneupory, No. 7, 41–46 (2004).
V. A. Kopeikin and D. N. Poluboyarinov, “The phase composition of high-alumina ceramics,” Ogneupory, No. 12, 566–572 (1960).
Author information
Authors and Affiliations
Additional information
Translated from Novye Ogneupory, No. 9, pp. 41 – 47, September, 2004.
Continuation of a series of communications started in Novye Ogneupory, No. 7, 2004.
Rights and permissions
About this article
Cite this article
Vakalova, T.V., Ivanchenkov, A.V., Pogrebenkov, V.M. et al. Synthesis of mullite from oxides doped with topaz. Refract Ind Ceram 45, 441–445 (2004). https://doi.org/10.1007/s11148-005-0030-5
Received:
Issue Date:
DOI: https://doi.org/10.1007/s11148-005-0030-5