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Transformation of methanol to trimethylbenzene catalyzed by cadmium modified HZSM-5 zeolites

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Abstract

Cadmium-modified HZSM-5 zeolite (Cd/HZSM-5) was prepared by ultrasound-assisted impregnation and its catalytic performance for methanol to aromatics (MTA) was investigated. It was characterized by means of XRD, SEM, TEM, Py-IR, N2 adsorption/desorption, NH3-TPD and XPS. Cd species distribute in the surface of the HZSM-5 zeolite, decreasing the crystallinity and increasing the Lewis acidity strength. Under the operating reaction condition of temperature at 400 °C, pressure at 0.1 MPa and space velocity of 1.896 h−1, 1.4 wt% Cd/HZSM-5 zeolites showed good catalytic activity for MTA with the aromatic’s selectivity of 71.1%. Compared with that of about 7.5% over HZSM-5, the trimethylbenzene isomers in aromatics is 86.6% and the main product is 1,2,4-trimethylbenzene with selectivity of 34.0% in all products and 86.5% in trimethylbenzene isomers over 1.4 wt% Cd/HZSM-5 zeolites.

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Acknowledgements

The authors express their gratitude for financial support from the National Natural Science Foundation of China (No. 21865031).

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Authors and Affiliations

  1. College of Chemical & Chemical Engineering, Northwest Normal University, Lanzhou, 730070, China

    Haifeng Tian, Duoyong Shi, Lei Yu, Fei Zha, Xiaohua Tang, Yue Chang & Xiaojun Guo

  2. Key Laboratory of Eco-Functional Polymer Materials of the Ministry of Education, Lanzhou, 730070, China

    Yue Chang

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  1. Haifeng Tian
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Correspondence to Fei Zha.

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Tian, H., Shi, D., Yu, L. et al. Transformation of methanol to trimethylbenzene catalyzed by cadmium modified HZSM-5 zeolites. Reac Kinet Mech Cat 135, 333–348 (2022). https://doi.org/10.1007/s11144-021-02144-z

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