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Investigation of the ozone-induced oxidation of soot over LaMnO3 catalyst using O3/O2 temperature-programmed desorption experiments

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Abstract

In this study, we investigated how the catalytic redox cycle occurs over a lanthanum manganese oxide (LaMnO3) catalyst when applied to the ozone-induced oxidation of soot. This was accomplished by tracking the catalysis using O3/O2 temperature-programmed desorption coupled with X-ray photoelectron spectroscopy (XPS). We prepared the catalyst by the citric acid sol–gel method to obtain a catalyst with a uniform perovskite phase and improved specific surface area. The catalyst was remarkably active in promoting ozone-induced soot oxidation within the temperature range of 25–125 °C. The active oxygen species were superoxide ions combined with Mn4+ ions on the catalyst surface. It was presumed the superoxide ion migrates over the surface Mn4+ sites and either desorbs as molecular oxygen or oxidizes the soot particles if it reaches the interface between soot and catalyst particles. The redox cycle was completed by the Mn4+-to-Mn3+ transition, which accompanied the detachment of superoxide ions. No evidence was found to support the involvement of the bulk phase of the catalyst with the redox cycle. The ozone-induced redox cycle was presumed to exclusively occur on the surface of the catalyst.

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Acknowledgements

This research was supported by Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Science & ICT (MSIT) (NRF-2016R1A5A1009592).

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Authors and Affiliations

  1. Interdisciplinary Program in Advanced Functional Materials and Devices Development, Kangwon National University, Chuncheon-Si, 24341, Republic of Korea

    Tae Uk Park, So Min Jin & Dae-Won Lee

  2. Department of Chemical Engineering, Kangwon National University, Chuncheon-Si, 24341, Republic of Korea

    Dae-Won Lee

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  1. Tae Uk Park
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  2. So Min Jin
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Contributions

Dae-Won Lee contributed to the study conception and design. Material preparation, data collection and analysis were performed by Tae Uk Park and So Min Jin. The first draft of the manuscript was written by D-WL and all authors commented on previous versions of the manuscript. All authors read and approved the final manuscript.

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Correspondence to Dae-Won Lee.

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Park, T.U., Jin, S.M. & Lee, DW. Investigation of the ozone-induced oxidation of soot over LaMnO3 catalyst using O3/O2 temperature-programmed desorption experiments. Reac Kinet Mech Cat 133, 259–276 (2021). https://doi.org/10.1007/s11144-021-01977-y

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