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Hydrodesulfurization reactions group kinetics of “vacuum gas oil–deasphalted vacuum residues–heavy coker gasoil” feedstock in the presence of a Ni6–PMonW12-n/γ-Al2O3 catalysts

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Abstract

The organosulfur compounds of mixed raw materials—vacuum gas oil in a mixture with heavy coking gas oil reactions group kinetic were investigated during hydrotreating at a hydrogen pressure of 5 MPa at various temperatures (360, 390, 420 °C) and LHSV of 0.5, 1.0, 2.0 and 4.0 h−1 in the presence of Ni6–MonW12-n/γ-Al2O3 sulfide catalysts, prepared on the base of phosphoromolybdenum and phosphorotungstenheteropolyacids. The total sulfur content was determined in feed and hydrogenates. A kinetic model describes the process of hydrodesulfurization of vacuum gas oil in hydrotreating on Ni6–MonW12-n/γ-Al2O3 catalysts based on phosphomolybdenum and phosphotungsten heteropolyacides (HPAs) has been selected. The adequacy of the kinetic model of the 2nd order was verified by means of the coefficient of determination and based on the values of the Fisher criterion. The optimal modes of the vacuum distillate hydrotreating process may be selected on the base of obtained data on the kinetics of hydrodesulfurization (HDS) reactions. The kinetic characteristics of the HDS and hydrodearomatization (HDA) reactions of the mixed feed compounds on Ni6–MonW12-n/γ-Al2O3 catalysts based on phosphor–molybdenum and phosphotungsten HPA were determined with the usage of chosen model. The Ni6PMo12/γ-Al2O3 catalyst was most active one in the HDS reaction. The activity of catalyst samples in hydrogenation reactions was investigated. It was shown that the most active sample is Ni6PMo4W8/γ-Al2O3.

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Acknowledgements

This work was financially supported by the Government of the Russian Federation. Resolution No. 220 dated April 9, 2010 Grant No. 14.Z50.31.0038 dated February 20, 2017.

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Authors and Affiliations

  1. Samara State Technical University, Molodogvardeyskaya street, 244, 443100, Samara, Russia

    N. M. Maximov, A. V. Moiseev, P. S. Solmanov, N N. Tomina, I. I. Zanozina & A. A. Pimerzin

  2. Middle Volga Research Institute for Oil Refining, Novokuibyshevsk, Nauchnaya street, 1, 446200, Samara, Russia

    I. I. Zanozina

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  1. N. M. Maximov
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  2. A. V. Moiseev
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Maximov, N.M., Moiseev, A.V., Solmanov, P.S. et al. Hydrodesulfurization reactions group kinetics of “vacuum gas oil–deasphalted vacuum residues–heavy coker gasoil” feedstock in the presence of a Ni6–PMonW12-n/γ-Al2O3 catalysts. Reac Kinet Mech Cat 132, 877–892 (2021). https://doi.org/10.1007/s11144-021-01953-6

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