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Selective hydrogenation of crotonaldehyde over Ir/BN catalysts: kinetic investigation and Ir particle size effect

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Abstract

A series of Ir/BN catalysts with same Ir contents (2 wt%) were calcined at different temperatures and tested for gas phase selective hydrogenation of crotonaldehyde. It was found that the thermal treatment exerted significant impacts on the structural and electronic properties of the 2Ir/BN catalysts. The catalyst calcined at 500 °C (2Ir/BN-5) showed the best performance, with a steady state of conversion of ca. 21% and a crotyl alcohol selectivity of ca. 83% at reaction temperature of 80 °C. Kinetic analysis indicated that the enhanced activity on the 2Ir/BN-5 catalyst was related to its higher surface coverage of crotonaldehyde because of the presence of small Ir particles (with a mean diameter of 3.4 nm) compared to those in the catalyst calcined at 600 °C (2Ir/BN-6, with a mean diameter of 4.4 nm). Also, the surface of the Ir species in the 2Ir/BN-5 catalyst are more electron-enriched compared to that in the 2Ir/BN-6, which suppressed the adsorption of C=C bond and thus improves the selectivity to CROL.

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References

  1. Saudan LA (2007) Acc Chem Res 40:1309–1319

    Article  CAS  PubMed  Google Scholar 

  2. Englisch M, Ranade VS, Lercher JA (1997) J Mol Catal A Chem 121:69–80

    Article  CAS  Google Scholar 

  3. Dandekar A, Vannice MA (1999) J Catal 183:344–354

    Article  CAS  Google Scholar 

  4. Silvestre-Albero J (2002) J Catal 210:127–136

    Article  CAS  Google Scholar 

  5. Concepción P, Corma A, Silvestre-Albero J, Franco V, Chane-Ching JY (2004) J Am Chem Soc 126:5523–5532

    Article  PubMed  Google Scholar 

  6. Ammari F, Lamotte J, Touroude R (2004) J Catal 221:32–42

    Article  CAS  Google Scholar 

  7. Ammari F, Milone C, Touroude R (2005) J Catal 235:1–9

    Article  CAS  Google Scholar 

  8. Ramos-Fernández EV, Samaranch B, de la Piscina PR, Homs N, Fierro JLG, Rodríguez-Reinoso F, Sepúlveda-Escribano A (2008) Appl Catal A Gen 349:165–169

    Article  Google Scholar 

  9. Hidalgo-Carrillo J, Aramendía MA, Marinas A, Marinas JM, Urbano FJ (2010) Appl Catal A Gen 385:190–200

    Article  CAS  Google Scholar 

  10. Yang X, Mueanngern Y, Baker QA, Baker LR (2016) Catal Sci Technol 6:6824–6835

    Article  CAS  Google Scholar 

  11. Englisch M, Jentys A, Lercher JA (1997) J Catal 166:25–35

    Article  CAS  Google Scholar 

  12. Weng Z, Zaera F (2018) ACS Catal 8:8513–8524

    Article  CAS  Google Scholar 

  13. Bailie JE, Hutchings G (1999) Chem Commun 21:2151–2152

    Article  Google Scholar 

  14. Zanella R, Louis C, Giorgio S, Touroude R (2004) J Catal 223:328–339

    Article  CAS  Google Scholar 

  15. Claus P (2005) Appl Catal A Gen 291:222–229

    Article  CAS  Google Scholar 

  16. Campo B, Volpe M, Ivanova S, Touroude R (2006) J Catal 242:162–171

    Article  CAS  Google Scholar 

  17. Lin H, Zheng J, Zheng X, Gu Z, Yuan Y, Yang Y (2015) J Catal 330:135–144

    Article  CAS  Google Scholar 

  18. Chen HY, Chang CT, Chiang SJ, Liaw BJ, Chen YJ (2010) Appl Catal A Gen 381:209–215

    Article  CAS  Google Scholar 

  19. Campo BC, Ivanova S, Gigola C, Petit C, Volpe MA (2008) Catal Today 133–135:661–666

    Article  Google Scholar 

  20. Guzmán C, Angel GD, Fierro JLG, Bertin V (2010) Top Catal 53:1142–1144

    Article  Google Scholar 

  21. Hong X, Li B, Wang Y, Lu J, Hu G, Luo M (2013) Appl Surf Sci 270:388–394

    Article  CAS  Google Scholar 

  22. Tamura M, Tokonami K, Nakagawa Y, Tomishige K (2016) ACS Catal 6:3600–3609

    Article  CAS  Google Scholar 

  23. Tamura M, Tokonami K, Nakagawa Y, Tomishige K (2017) ACS Sustain Chem Eng 5:3685–3697

    Article  CAS  Google Scholar 

  24. Yuan JF, Luo CQ, Yu Q, Jia AP, Hu GS, Lu JQ, Luo MF (2016) Catal Sci Technol 6:4294–4305

    Article  CAS  Google Scholar 

  25. Yu Q, Bando KK, Yuan JF, Luo CQ, Jia AP, Hu GS, Lu JQ, Luo MF (2016) J Phys Chem C 120:8663–8673

    Article  CAS  Google Scholar 

  26. Ning X, Xu YM, Wu AQ, Tang C, Jia AP, Luo MF, Lu JQ (2019) Appl Surf Sci 463:463–473

    Article  CAS  Google Scholar 

  27. Kennedy G, Baker LR, Somorjai GA (2014) Angew Chem Int Ed 53:3405–3408

    Article  CAS  Google Scholar 

  28. He S, Xie L, Che M, Chan HC, Yang L, Shi Z, Tang Y, Gao Q (2016) J Mol Catal A Chem 425:248–254

    Article  CAS  Google Scholar 

  29. Ryndin YA, Santini CC, Prat D, Basset JM (2000) J Catal 190:364–373

    Article  CAS  Google Scholar 

  30. Tamura M, Tokonami K, Nakagawa Y, Tomishige K (2013) Chem Commun 49:7034–7036

    Article  CAS  Google Scholar 

  31. Tamura M, Yonezawa D, Oshino T, Nakagawa Y, Tomishige K (2017) ACS Catal 7:5103–5111

    Article  CAS  Google Scholar 

  32. Xu YM, Zheng WB, Hu YM, Tang C, Jia AP, Lu JQ (2020) J Catal 381:222–233

    Article  CAS  Google Scholar 

  33. Pakdel A, Bando Y, Golberg D (2014) Chem Soc Rev 43:934–959

    Article  CAS  PubMed  Google Scholar 

  34. Lin S, Ye XX, Johnson RS, Guo H (2013) J Phys Chem C 117:17319–17326

    Article  CAS  Google Scholar 

  35. Kaneko S, Izuka M, Takahashi A, Ohshima M, Kurokawa H, Miura H (2012) Appl Catal A Gen 427–428:85–91

    Article  Google Scholar 

  36. Amrousse R, Hori K, Fetimi W (2012) Catal Commun 27:174–178

    Article  CAS  Google Scholar 

  37. Hernández-Cristóbal O, Díaz G, Gómez-Cortés A (2014) IndEngChem Res 53:10097–10104

    Google Scholar 

  38. Maurer F, Jelic J, Wang J, Gänzler A, Dolcet P, Wöll C, Wang Y, Studt F, Casapu M, Grunwaldt JD (2020) Nat Catal 3:824–833

    Article  CAS  Google Scholar 

  39. Dong JH, Fu Q, Li HB, Xiao JP, Yang B, Zhang BS, Bai YX, Song TY, Zhang TK, Gao LJ, Cai J, Zhang H, Liu Z, Bao XH (2020) J Am Chem Soc 142:17167–17174

    Article  CAS  PubMed  Google Scholar 

  40. Dong JH, Fu Q, Jiang Z, Mei BB, Bao XH (2018) J Am Chem Soc 140:13808–13816

    Article  CAS  PubMed  Google Scholar 

  41. Solymosi F, Rsako J (1980) J Catal 62:253–263

    Article  CAS  Google Scholar 

  42. Solymosi F, Novák E, Molnár A (1990) J Phys Chem 94:7250–7255

    Article  CAS  Google Scholar 

  43. Haneda M, Fujitani T, Hamada H (2006) J Mol Catal A Chem 256:143–148

    Article  CAS  Google Scholar 

  44. Merlo AB, Santori GF, Sambeth J, Siri GJ, Casella ML, Ferretti OA (2006) Catal Commun 7:204–208

    Article  CAS  Google Scholar 

  45. Zhu L, Lu J, Xie G, Chen P, Luo M (2012) Chin J Catal 33:348–353

    CAS  Google Scholar 

  46. Zhu L, Lu JQ, Chen P, Hong X, Xie GQ, Hu GS, Luo MF (2012) J Mol Catal A Chem 361–362:52–57

    Article  Google Scholar 

  47. Wang XX, Zheng HY, Liu XJ, Xie GQ, Lu JQ, Jin LY, Luo MF (2010) Appl Catal A Gen 388:134–140

    Article  CAS  Google Scholar 

  48. Reyes P, del Carmen AM, Melián-Cabrera IV, Granados ML, García FJL (2002) J Catal 208:229–237

    Article  CAS  Google Scholar 

  49. Lochař V, Smoláková L (2009) Reac Kinet Catal Lett 96:117–123

    Article  Google Scholar 

  50. Jesus JC, Zaera F (1999) Surf Sci 430:99–115

    Article  Google Scholar 

Download references

Acknowledgement

This work is financially supported by the National Natural Science Foundation of China (No. 21773212).

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Authors and Affiliations

  1. Zhejiang Key Laboratory for Reactive Chemistry On Solid Surfaces, Key Laboratory of the Ministry of Education for Advanced Catalysis Materials, Institute of Physical Chemistry, Zhejiang Normal University, Jinhua, 321004, China

    Yi-Ming Hu, Wan-Bin Zheng, Ai-Ping Jia, Meng-Fei Luo, Cen Tang & Ji-Qing Lu

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  1. Yi-Ming Hu
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  2. Wan-Bin Zheng
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Correspondence to Ji-Qing Lu.

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Hu, YM., Zheng, WB., Jia, AP. et al. Selective hydrogenation of crotonaldehyde over Ir/BN catalysts: kinetic investigation and Ir particle size effect. Reac Kinet Mech Cat 132, 301–315 (2021). https://doi.org/10.1007/s11144-021-01933-w

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