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Ru-doped transition metal catalysts for liquid-phase Fischer–Tropsch synthesis

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Abstract

In this paper the catalytic activity of the Ru-doped polymer-based catalysts synthesized by the hydrothermal deposition is described. The catalytic properties of the synthesized systems were studied in the liquid-phase Fischer–Tropsch synthesis for the production of liquid gasoline and diesel-range hydrocarbons. The catalysts showed high CO hydrogenating activity allowing more than 20% of CO conversion to be obtained for one cycle. The yield of liquid hydrocarbons (mainly linear C5-C13) was found to be more than 80%. The addition of the ruthenium to the commonly used Co, Ni, and Fe enhances both the catalytic activity and the yield of the liquid hydrocarbons. The catalysts seem to be stable for minimum 80 h on stream.

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Abbreviations

FTS:

Fischer–Tropsch synthesis

MOF:

Metal–organic frameworks

HPS:

Hypercrosslinked polystyrene

GCMS:

Gas chromatography mass-specrtometry

DTG:

Differencial thermogravimetry

XPS:

X-ray photoelectron spectroscopy

TEM:

Transmission electron microscopy

TGA:

Thermogravimetric analysis

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Acknowledgements

The current work is financially supported by the Ministry of Science and Higher Education of the Russian Federation and the Russian Foundation for Basic Research (Grant 18-29-06004). Authors thank Dr. Liudmila Bronstein (Indiana University) for the help in TEM study, Dr. Alexey Bykov, Prof. Alexander Sidorov, and Dr, Yury Lugovoy (Tver State Technical University) for the help in XPS, BET and TGA study. Mariia Markova thanks the Foundation for the promotion of small-scale enterprises in the scientific and technical sphere (Program U.M.N.I.K, Grant 0059483) for the financial support.

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Authors and Affiliations

  1. Tver State Technical University, A. Nikitina str. 22, Tver, Russia, 170026

    Mariia E. Markova, Alexandra V. Gavrilenko, Antonna A. Stepacheva, Valentina G. Matveeva, Mikhail G. Sulman & Esther M. Sulman

  2. Tver State University, Zhelyabova str. 33, Tver, Russia, 170100

    Mariia E. Markova & Valentina G. Matveeva

  3. D.I.  Mendeleev University of Chemical Technology of Russia, Miusskaya sq., 9, Moscow, Russia, 125047

    Viktor I. Panfilov

Authors
  1. Mariia E. Markova
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  2. Alexandra V. Gavrilenko
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  3. Antonna A. Stepacheva
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  4. Valentina G. Matveeva
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  5. Mikhail G. Sulman
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  6. Viktor I. Panfilov
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  7. Esther M. Sulman
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Correspondence to Antonna A. Stepacheva.

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Markova, M.E., Gavrilenko, A.V., Stepacheva, A.A. et al. Ru-doped transition metal catalysts for liquid-phase Fischer–Tropsch synthesis. Reac Kinet Mech Cat 130, 813–823 (2020). https://doi.org/10.1007/s11144-020-01800-0

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  • DOI: https://doi.org/10.1007/s11144-020-01800-0

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