Skip to main content
Log in

Photocatalytic degradation of rhodamine B and methylene blue by electrochemically prepared nano titanium dioxide/reduced graphene oxide/poly (methyl methacrylate) nanocomposite

  • Full Paper
  • Published:
Reaction Kinetics, Mechanisms and Catalysis Aims and scope Submit manuscript

Abstract

Composite of electrochemically prepared nano titanium dioxide/reduced graphene oxide/poly (methyl methacrylate) has been successfully synthesized. The homogeneous titanium dioxide nanoparticles (TiO2 NPs) and reduced graphene oxide were prepared individually and composites of titanium dioxide nanoparticles/reduced graphene oxide (TiO2/RGO) in different ratios were then prepared under sonication. Nano titanium dioxide/reduced graphene oxide/poly(methyl methacrylate) (TiO2/RGO/PMMA) composite were prepared subsequently. The composites were characterized by X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), transmission electron microscopy (TEM), scanning electron microscopy (SEM) and electron dispersive spectrometer (EDS) for elemental analysis. Due to the long and great research interest as well as importance of developing new and efficient techniques in dyes degradation, methylene blue (MB) and Rhodamine B (RhB) were selected as two candidate to examine photocatalytic performance of the composites under 15 W UV-C lamp irradiation. Recovery of the TiO2/RGO/PMMA composite also revealed slight decrease in photocatalytic performance after four cycles.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7

Similar content being viewed by others

References

  1. Bharathi KS, Ramesh ST (2013) Removal of dyes using agricultural waste as low-cost adsorbents: a review. Appl Water Sci 3:773–790

    Article  Google Scholar 

  2. Merouani S, Hamdaoui O, Saoudi F, Chiha M (2010) Sonochemical degradation of Rhodamine B in aqueous phase: effects of additives. Chem Eng J 158:550–557

    Article  CAS  Google Scholar 

  3. Boczkaj G, Fernandes A (2017) Wastewater treatment by means of advanced oxidation processes at basic pH conditions: a review. Chem Eng J 320:608–633

    Article  CAS  Google Scholar 

  4. Dewil R, Mantzavinos D, Poulios I, Rodrigo MA (2017) New perspectives for advanced oxidation processes. J Environ Manag 195:93–99

    Article  CAS  Google Scholar 

  5. Kamalan Kirubaharan AM, Selvaraj M, Maruthan K, Jeyakumar D (2012) Synthesis and characterization of nanosized titanium dioxide and silicon dioxide for corrosion resistance applications. J Coat Technol Res 9:163–170

    Article  CAS  Google Scholar 

  6. Saeed M, Muneer M, Mumtaz N, Siddique M, Akram N (2018) Ag-Co3O4: Synthesis, characterization and evaluation of its photo-catalytic activity towards degradation of rhodamine B dye in aqueous medium. Chin J Chem Eng 26:1264–1269

    Article  CAS  Google Scholar 

  7. Fuentes KM, Betancourt P, Marrero S, García S (2017) Photocatalytic degradation of phenol using doped titania supported on photonic SiO2 spheres. Reac Kinet Mech Cat 120:403–415

    Article  CAS  Google Scholar 

  8. Castellanos NJ, Martinez Rojas Z, Camargo HA, Biswas S, Granados-Oliveros G (2019) Congo red decomposition by photocatalytic formation of hydroxyl radicals (·OH) using titanium metal–organic frameworks. Transit Met Chem 44:77–87

    Article  CAS  Google Scholar 

  9. Carević MV, Abazović ND, Savić TD, Novaković TB, Pjević DJ, Čomor MI (2018) Binary oxide ceramics for enhanced phenols degradation under simulated Solar light. J Am Ceram Soc 101(4):1420–1431

    Article  Google Scholar 

  10. Prasai B, Cai B, Underwood MK, Lewis JP, Drabold DA (2012) Properties of amorphous and crystalline titanium dioxide from first principles. J Mater Sci 47:7515–7521

    Article  CAS  Google Scholar 

  11. Alzamani M, Shokuhfar M, Eghdam E, Mastali S (2013) Influence of catalyst on structural and morphological properties of TiO2 nanostructured films prepared by sol–gel on glass. Prog Nat Sci Mater Int 23:77–84

    Article  Google Scholar 

  12. Martínez C, Canle LM, Fernández MI, Santaballa JA, Faria J (2011) Kinetics and mechanism of aqueous degradation of carbamazepine by heterogeneous photocatalysis using nanocrystalline TiO2, ZnO and multi-walled carbon nanotubes–anatase composites. Appl Catal B 102:563–571

    Article  Google Scholar 

  13. Ghasemi M, Amoozadeh A, Kowsari E (2017) Chitosan-functionalized nano-titanium dioxide: a novel and highly efficient nanocatalyst for the synthesis of 2,4,5-trisubstituted imidazoles under solvent-free conditions. Reac Kinet Mech Cat 120:605–617

    Article  CAS  Google Scholar 

  14. Binas V, Venieri D, Kotzias D, Kiriakidis G (2017) Modified TiO2 based photocatalysts for improved air and health quality. J Materiomics 3:3–16

    Article  Google Scholar 

  15. Zhang D (2010) Enhanced photocatalytic activity for titanium dioxide by co-modification with copper and iron. Transit Met Chem 35:933–938

    Article  CAS  Google Scholar 

  16. Than LD, Luong NS, Ngo VD, Tien NM, Dung TN, Nghia NM (2017) Highly visible light activity of nitrogen doped TiO2 prepared by sol-gel approach. J Electron Mater 46:158–166

    Article  CAS  Google Scholar 

  17. de Luna MDG, Lin JCT, Gotostos MJN, Lu MC (2016) Photocatalytic oxidation of acetaminophen using carbon self-doped titanium dioxide. Sustain Environ Res 26:161–167

    Article  Google Scholar 

  18. Andoshe DM, Yim K, Sohn W (2018) One-pot synthesis of sulfur and nitrogen codoped titanium dioxide nanorod arrays for superior photoelectrochemical water oxidation. Appl Catal B 234:213–222

    Article  CAS  Google Scholar 

  19. Song G, Chu Z, Jin W (2015) Enhanced performance of g-C3N4/TiO2 photocatalysts for degradation of organic pollutants under visible light. Chin J Chem Eng 23:1326–1334

    Article  CAS  Google Scholar 

  20. Yadav HM, Kim JS (2016) Solvothermal synthesis of anatase TiO2-graphene oxide nanocomposites and their photocatalytic performance. J Alloys Compd 688:123–129

    Article  CAS  Google Scholar 

  21. Jo WK, Kumar S, Isaacs MA, Lee AF, Karthikeyan S (2017) Cobalt promoted TiO2/GO for the photocatalytic degradation of oxytetracycline and Congo Red. Appl Catal B 201:159–168

    Article  CAS  Google Scholar 

  22. Liu S, Sun H, Liu S, Wang S (2013) Graphene facilitated visible light photodegradation of methylene blue over titanium dioxide photocatalysts. Chem Eng J 214:298–303

    Article  CAS  Google Scholar 

  23. Wang D, Li X, Chen J, Tao X (2012) Enhanced photoelectrocatalytic activity of reduced graphene oxide/TiO2 composite films for dye degradation. Chem Eng J 198–199:547–554

    Article  Google Scholar 

  24. Alamelu K, Raja V, Shiamala L, Jaffar Ali BM (2018) Biphasic TiO2 nanoparticles decorated graphene nanosheets for visible light driven photocatalytic degradation of organic dyes. Appl Surf Sci 430:145–154

    Article  CAS  Google Scholar 

  25. Brindha A, Sivakumar T (2017) Visible active N, S co-doped TiO2/graphene photocatalysts for the degradation of hazardous dyes. J Photochem Photobiol A 340:146–156

    Article  CAS  Google Scholar 

  26. Roşu M-C, Socaci C, Floare-Avram V, Borodi G, Pogăcean F, Coroş M (2016) Photocatalytic performance of graphene/TiO2-Ag composites on amaranth dye degradation. Mater Chem Phys 179:232–241

    Article  Google Scholar 

  27. Klaysri R, Wichaidit S, Piticharoenphun S, Mekasuwandumrong O, Praserthdam P (2016) Synthesis of TiO2-grafted onto PMMA film via ATRP: using monomer as a coupling agent and reusability in photocatalytic application. Mater Res Bull 83:640–648

    Article  CAS  Google Scholar 

  28. Cantarella M, Sanz R, Buccheri MA, Ruffino F, Rappazzo G, Scalese S (2016) Immobilization of nanomaterials in PMMA composites for photocatalytic removal of dyes, phenols and bacteria from water. J Photochem Photobiol A 321:1–11

    Article  CAS  Google Scholar 

  29. Raliya R, Avery C, Chakrabarti S, Biswas P (2017) Photocatalytic degradation of methyl orange dye by pristine titanium dioxide, zinc oxide, and graphene oxide nanostructures and their composites under visible light irradiation. Appl Nanosci 7:253–259

    Article  CAS  Google Scholar 

  30. Cantarella M, Sanz R, Buccheri MA, Romano L, Privitera V (2016) PMMA/TiO2 nanotubes composites for photocatalytic removal of organic compounds and bacteria from water. Mater Sci Semicond Process 42:58–61

    Article  CAS  Google Scholar 

  31. Gunputh U, Le H, Handy R, Tredwin C (2018) Anodised TiO2 nanotubes as a scaffold for antibacterial silver nanoparticles on titanium implants. Mater Sci Eng C 91:638–644

    Article  CAS  Google Scholar 

  32. Yuan XZ, Sergio P, Emanuele T, Giuliano G, Franco C, Vittorio M (2013) The exfoliation of graphene in liquids by electrochemical, chemical, and sonication-assisted techniques: a nanoscale study. Adv Funct Mater 23(37):4684–4693

    Google Scholar 

  33. Atchudan R, Jebakumar Immanuel Edison TN, Perumal S, Karthikeyan D, Lee YR (2017) Effective photocatalytic degradation of anthropogenic dyes using graphene oxide grafting titanium dioxide nanoparticles under UV-light irradiation. J Photochem Photobiol A 333:92–104

    Article  CAS  Google Scholar 

  34. Venkatachalam N, Palanichamy M, Murugesan V (2007) Sol–gel preparation and characterization of alkaline earth metal doped nano TiO2: efficient photocatalytic degradation of 4-chlorophenol. J Mol Catal A 273:177–185

    Article  CAS  Google Scholar 

  35. Cheong YL, Yam FK, Ooi YW, Hassan Z (2014) Room-temperature synthesis of nanocrystalline titanium dioxide via electrochemical anodization. Mater Sci Semicond Process 26:130–136

    Article  CAS  Google Scholar 

  36. Nguyen-Phan TD, Pham VH, Shin EW, Pham HD, Kim S, Chung JS (2011) The role of graphene oxide content on the adsorption-enhanced photocatalysis of titanium dioxide/graphene oxide composites. Chem Eng J 170:226–232

    Article  CAS  Google Scholar 

Download references

Acknowledgement

The authors gratefully thank University of Zanjan for financial supports.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Masoomeh Torabi Momen.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Electronic supplementary material

Below is the link to the electronic supplementary material.

Supplementary material 1 (DOCX 1866 kb)

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Torabi Momen, M., Piri, F. & Karimian, R. Photocatalytic degradation of rhodamine B and methylene blue by electrochemically prepared nano titanium dioxide/reduced graphene oxide/poly (methyl methacrylate) nanocomposite. Reac Kinet Mech Cat 129, 1145–1157 (2020). https://doi.org/10.1007/s11144-020-01722-x

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11144-020-01722-x

Keywords

Navigation