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Ni catalyst synthesized by hydrothermal deposition on the polymeric matrix in the supercritical deoxygenation of fatty acids

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Abstract

In the current work, the use of Ni-containing catalyst on the base of hypercrosslinked polystyrene in the stearic acid (SA) hydrodeoxygenation (HDO) in the medium of supercritical n-hexane is presented. The catalyst was synthesized by the hydrothermal deposition of Ni-containing particles into the pores of the polymeric matrix in the medium of superheated water. It was found that the catalyst is characterized by the high surface area and the uniform deposition of the active phase on the catalyst surface. Ni in the catalyst is represented by NiOOH. The mean particle diameter of the active phase was found to be 5.5 nm. The catalyst showed high efficiency in the SA HDO in the medium of supercritical n-hexane reaching the C16–C17 yield up to 90 at 100% substrate conversion. It was shown that the catalyst maintained its activity in minimum five consecutive runs without sufficient loose selectivity.

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Abbreviations

HDO:

Hydrodeoxygenation

HPS:

Hypercrosslinked polystyrene

SA:

Stearic acid

FAMEs:

Fatty acid methyl esters

UV-spectroscopy:

Ultraviolet spectroscopy

XPS:

X-ray photoelectron spectroscopy

TEM:

Transmission electron microscopy

TGA:

Thermogravimetric analysis

BE:

Binding energy

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Acknowledgements

Authors thank the Russian Science Foundation [Grant Number 17-79-10089] for the financial support.

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Authors and Affiliations

  1. Tver State Technical University, A. Nikitina str. 22, Tver, Russia, 170026

    Antonina A. Stepacheva, Alexey V. Bykov, Alexander I. Sidorov, Mikhail G. Sulman, Valentina G. Matveeva & Esther M. Sulman

  2. Tver State University, Zhelyabova str. 33, Tver, Russia, 170100

    Mariia E. Markova & Valentina G. Matveeva

  3. A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Science, Vavilova str. 28, Moscow, Russia, 119991

    Mikhail G. Sulman

Authors
  1. Antonina A. Stepacheva
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  2. Mariia E. Markova
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  3. Alexey V. Bykov
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  4. Alexander I. Sidorov
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  5. Mikhail G. Sulman
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  6. Valentina G. Matveeva
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  7. Esther M. Sulman
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Correspondence to Antonina A. Stepacheva.

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Stepacheva, A.A., Markova, M.E., Bykov, A.V. et al. Ni catalyst synthesized by hydrothermal deposition on the polymeric matrix in the supercritical deoxygenation of fatty acids. Reac Kinet Mech Cat 125, 213–226 (2018). https://doi.org/10.1007/s11144-018-1424-y

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