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Synthesis and characterization of Ce-SBA-15 supported cesium catalysts and their catalytic performance for synthesizing methyl acrylate

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Abstract

A series of Ce-SBA-15 mesoporous materials were synthesized through a direct hydrothermal method and further impregnated with different amounts of Cs. The catalysts were characterized by XRD, XPS, SEM, NH3-TPD, CO2-TPD, FT-IR and N2 adsorption–desorption isotherm analyses. The XRD and N2 adsorption–desorption isotherm results showed that the Ce successfully incorporated into the framework of SBA-15, which was favorable for the generation of mesoporous materials with high specific surface areas, large pore volumes and narrow pore size distribution. The incorporation of Ce changed the acid–base properties of the support and promoted the dispersion of Cs species. NH3–CO2 TPD results indicated that a number of medium-strong acid and base sites existed in the 10Cs/Ce-SBA-15(10) catalyst, which made it suitable as a catalyst for the aldol condensation of methyl acetate with formaldehyde to prepare methyl acrylate.

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Acknowledgements

This work was supported by the technology institute of Shanghai Huayi (Group) Company, Jilin Province Science and Technology research plan (key scientific research project). (No. 20150204020GX) and the National Science Foundation of China (Grant No. 21473074).

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Authors and Affiliations

  1. Key Laboratory of Surface and Interface Chemistry of Jilin Province, College of Chemistry, Jilin University, Qianjin Road 2699, Changchun, 130012, People’s Republic of China

    Mengmeng Hao, Wanchun Zhu, Qiang Bao, Jianbiao Yan & Zhenlu Wang

  2. Shanghai Huayi (Group) Company Technology Research Institute, Longwu Road 4600, Shanghai, 200241, People’s Republic of China

    Chunlei Zhang, Chunli Ning, Yi Zhang & Jianbiao Yan

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  1. Mengmeng Hao
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  2. Wanchun Zhu
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  3. Chunlei Zhang
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  4. Chunli Ning
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  5. Yi Zhang
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  6. Qiang Bao
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Correspondence to Zhenlu Wang.

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Hao, M., Zhu, W., Zhang, C. et al. Synthesis and characterization of Ce-SBA-15 supported cesium catalysts and their catalytic performance for synthesizing methyl acrylate. Reac Kinet Mech Cat 125, 395–409 (2018). https://doi.org/10.1007/s11144-018-1419-8

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  • DOI: https://doi.org/10.1007/s11144-018-1419-8

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