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Synthesis of 3-picoline from acrolein dimethyl acetal and ammonia over NH4F-HF treated ZSM-5

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Abstract

The post-treated ZSM-5 was an effective catalyst for the synthesis of pyridine bases and therefore selecting suitable post-synthetic method was very crucial. In this work, a series of Mg-modified ZSM-5 with different forms was directly treated by HF-NH4F mixture solution, and then they acting as catalysts were for the first time employed for the reaction of acrolein dimethyl acetal, water and ammonia toward 3-picoline. The catalysts were characterized by means of XRD, SEM, EDX, FT-IR, 27Al MAS NMR, N2-physisorption, NH3-TPD and Py-IR techniques. The characterization results revealed that the fluorination had a great influence on the pore structure and acidity of catalysts, deriving from the simultaneous desilication and dealumination. These factors resulted in large changes on the catalytic activities toward the modified catalysts than the corresponding to parent ones.

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Acknowledgements

This work was supported by the Hunan Provincial Natural Science Foundation of China (2018JJ3427), the Educational Commission of Hunan Province (17C1361) and the Doctoral Scientific Research Foundation of the University of South China (2016XQD36).

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Authors and Affiliations

  1. School of Environmental and Safety Engineering, University of South China, Hengyang, 421001, China

    Cai-Wu Luo

  2. College of Chemistry and Chemical Engineering, Hunan Institute of Science and Technology, Yueyang, 414006, Hunan, China

    An Li

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  1. Cai-Wu Luo
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  2. An Li
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Correspondence to Cai-Wu Luo.

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Luo, CW., Li, A. Synthesis of 3-picoline from acrolein dimethyl acetal and ammonia over NH4F-HF treated ZSM-5. Reac Kinet Mech Cat 125, 365–380 (2018). https://doi.org/10.1007/s11144-018-1405-1

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  • DOI: https://doi.org/10.1007/s11144-018-1405-1

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