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More insight on the isothermal spreading of solid MoO3 into ZSM-5 zeolite

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Abstract

Pure MoO3 undergoes dehydration under helium stream between room temperature and 220 °C before being transformed into MoO2.87 and lost by evaporation at 650 °C. However, in the presence of NH4+–ZSM-5 zeolite (Mo/Al = 1), the dehydration of the mixture and the deammonization of the zeolite take place below 440 °C. In this water–rich atmosphere, a fraction of MoO3 is rehydrated and transformed into gaseous MoO2(OH)2 at 220–440 °C instead of being reduced. Despite the significant Mo weight loss, MoO2(OH)2 (g) reacts with ZSM-5 zeolite and is transformed into polymolybdate species upon 4 h of isothermal exchange at 500 °C. However, when the reaction time is prolonged from 4 to 8 h, the residual MoO3 undergoes an agglomeration before being transformed into mono- and dimolybdate species following 12 h of exchange. The determination of band gap energy by means of the diffuse reflectance spectroscopy allowed the identification of Mo species and the quantification of residual MoO3 (55% of the total Mo), which occupied the zeolite surface (46% of residual MoO3) and the internal cavities (9% of residual MoO3).

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Authors and Affiliations

  1. Laboratoire de Chimie des Matériaux et Catalyse, Faculté des Sciences de Tunis, Université de Tunis El Manar, Campus Universitaire Tunis El Manar, 2092, Tunis, Tunisia

    Faouzi Ayari, Emna Mannei, Mourad Mhamdi & Abdelhamid Ghorbel

  2. Faculté de Pharmacie de Monastir, Université de Monastir, Rue Avicenne, 5000, Monastir, Tunisia

    Faouzi Ayari

  3. Dpto. Química Inorgánica y Química Técnica, Facultad de Ciencias, Universidad Nacional de Educación a Distancia, Paseo Senda del Rey 9, 28040, Madrid, Spain

    Esther Asedegbega-Nieto & Antonio Ricardo Guerrero-Ruiz

  4. Institut Supérieur des Technologies Médicales de Tunis, Université de Tunis El Manar, 9 Avenue Docteur Zouhaier Essafi, 1006, Tunis, Tunisia

    Mourad Mhamdi

  5. Institut Charles Gerhardt Montpellier, UMR 5253, CNRS–UM–ENSCM, Matériaux Avancés pour la Catalyse et la Santé, ENSCM, 240 Avenue du Professeur Emile Jeanbrau, CS 60297, 34296, Montpellier Cedex 05, France

    Gérard Delahay

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  1. Faouzi Ayari
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  2. Emna Mannei
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Correspondence to Faouzi Ayari.

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Ayari, F., Mannei, E., Asedegbega-Nieto, E. et al. More insight on the isothermal spreading of solid MoO3 into ZSM-5 zeolite. Reac Kinet Mech Cat 124, 419–436 (2018). https://doi.org/10.1007/s11144-018-1357-5

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  • DOI: https://doi.org/10.1007/s11144-018-1357-5

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