Abstract
A series of silica supported silver catalysts (Ag/SiO2) with Ag loading ranging from 5% to 15% were fabricated by the ammonia-evaporation deposition–precipitation method. The effect of Ag contents on the catalytic performance of the catalysts in the selective hydrogenation of dimethyl oxalate (DMO) to methyl glycolate (MG) was investigated. The result indicates that the catalyst with a 10 wt% silver loading exhibits the best catalytic activity and excellent long-term stability of more than 150 h. Characteristic studies by N2 adsorption, TPR, XRD, and XPS show that the Ag content has a significant impact on the physicochemical properties of the Ag/SiO2 catalyst. Furthermore, the influence of some additives (B, Ni, La, Ce, and Mo) on the catalytic performance of the most active 10%Ag/SiO2 catalyst in the DMO hydrogenation to MG was also studied.
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Lee JS, Kim JC, Kim YG (1990) Methyl formate as a new building block in C1 chemistry. Appl Catal 57:1–30
He D, Huang W, Liu J, Zhu Q (1999) Condensation of formaldehyde and methyl formate to methyl glycolate and methyl methoxy acetate using heteropolyacids and their salts. Catal Today 51:127–134
Xu Y, Meh A, Yang G, Zhao Y, Chen Q, Li Z, Ma X (2016) Homogeneous catalytic kinetics of methyl glycolate hydrolysis. Chem Eng Technol 39:918–926
Sun Y, Wang H, Shen J, Liu H, Liu Z (2009) Highly effective synthesis of methyl glycolate with heteropolyacids as catalysts. Catal Commun 10:678–681
Barri SAI, Chadwick D (2011) Carbonylation of formaldehyde with zeolite catalysts. Catal Lett 141:749–753
Chen H, Tan J, Cui J, Yang X, Zheng H, Zhu Y, Li Y (2017) Promoting effect of boron oxide on Ag/SiO2 catalyst for the hydrogenation of dimethyl oxalate to methyl glycolate. Mol Catal 433:346–353
Wen C, Cui Y, Chen X, Zong B, Dai W (2015) Reaction temperature controlled selective hydrogenation of dimethyl oxalate to methyl glycolate and ethylene glycol over copper-hydroxyapatite catalysts. Appl Catal B 162:483–493
Cui Y, Wang B, Wen C, Chen X, Dai W (2016) Investigation of activated-carbon-supported copper catalysts with unique catalytic performance in the hydrogenation of dimethyl oxalate to methyl glycolate. ChemCatChem 8:527–531
Wang B, Cui Y, Wen C, Chen X, Dong Y, Dai W (2016) Role of copper content and calcination temperature in the structural evolution and catalytic performance of Cu/P25 catalysts in the selective hydrogenation of dimethyl oxalate. Appl Catal A 509:66–74
Zhao Y, Zhang Y, Wang Y, Zhang J, Xu Y, Wang S, Ma X (2017) Structure evolution of mesoporous silica supported copper catalyst for dimethyl oxalate hydrogenation. Appl Catal A 539:59–69
Yin A, Guo X, Dai W, Fan K (2010) High activity and selectivity of Ag/SiO2 catalyst for hydrogenation of dimethyl oxalate. Chem Commun 46:4348–4350
Yin A, Wen C, Dai W, Fan K (2011) Ag/MCM-41 as a highly efficient mesostructured catalyst for the chemoselective synthesis of methyl glycolate and ethylene glycol. Appl Catal B 108–109:90–99
Zheng J, Lin H, Zheng X, Duan X, Yuan Y (2013) Highly efficient mesostructured Ag/SBA-15 catalysts for the chemoselective synthesis of methyl glycolate by dimethyl oxalate hydrogenation. Catal Commun 40:129–133
Zheng J, Duan X, Lin H, Gu Z, Fang H, Li J, Yuan Y (2016) Silver nanoparticles confined in carbon nanotubes: on the understanding of the confinement effect and promotional catalysis for the selective hydrogenation of dimethyl oxalate. Nanoscale 8:5959–5967
Ouyang M, Wang Y, Zhang J, Zhao Y, Wang S, Ma X (2016) Three dimensional Ag/KCC-1 catalyst with a hierarchical fibrous framework for the hydrogenation of dimethyl oxalate. RSC Adv 6:12788–12791
Miyazawa K, Inagaki S (2000) Control of the microporosity within the pore walls of ordered mesoporous silica SBA-15. Chem Commun 21:2121–2122
Huang Z, Cui F, Kang H, Chen J, Zhang X, Xia C (2008) Highly dispersed silica-supported copper nanoparticles prepared by precipitation-gel method: a simple but efficient and stable catalyst for glycerol hydrogenolysis. Chem Mater 20:5090–5099
Ma L, Jia L, Guo X, Xiang L (2014) Catalytic activity of Ag/SBA-15 for low-temperature gas-phase selective oxidation of benzyl alcohol to benzaldehyde. Chin J Catal 35:108–119
Qu Z, Cheng M, Shi C, Bao X (2005) Low-temperature selective oxidation of CO in H2-rich gases over Ag/SiO2 catalysts. J Mol Catal A 239:22–31
Mo L, Wan A-H, Zheng X, Yeh CT (2009) Selective production of hydrogen from partial oxidation of methanol over supported silver catalysts prepared by method of redox coprecipitation. Catal Today 148:124–129
Gac W, Derylo-Marczewska A, Pasieczna-Patkowska S, Popivnyak N, Zukocinski G (2007) The influence of the preparation methods and pretreatment conditions on the properties of Ag-MCM-41 catalysts. J Mol Catal A 268:15–23
Männikkö M, Skoglundh M, Härelind H (2005) Methanol assisted lean NOx reduction over Ag-Al2O3—influence of hydrogen and silver loading. Top Catal 58:977–983
Zhou J, Duan X, Ye L, Zheng J, Li MM, Tsang SCE, Yuan Y (2015) Enhanced chemoselective hydrogenation of dimethyl oxalate to methyl glycolate over bimetallic Ag-Ni/SBA-15 catalysts. Appl Catal A 505:344–353
Zheng J, Lin H, Zheng X, Duan X, Yuan Y (2013) Efficient low-temperature selective hydrogenation of esters on bimetallic Au–Ag/SBA-15 catalyst. J Catal 297:110–118
Acknowledgements
The financial supports of Shanghai Municipal Science and Technology Commission (13ZR1441200) and Shanghai Municipal Education Commission (13YZ117) are gratefully acknowledged. The authors wish to express their great appreciation to the anonymous reviewers for their adequate suggestions and to Dr. Qiangsheng Guo for conducting the XPS measurements.
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Cheng, S., Mao, D., Guo, X. et al. Synthesis of methyl glycolate from the hydrogenation of dimethyl oxalate on Ag/SiO2 catalyst: the effects of Ag contents and promoters. Reac Kinet Mech Cat 126, 1067–1079 (2019). https://doi.org/10.1007/s11144-018-01527-z
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DOI: https://doi.org/10.1007/s11144-018-01527-z