Abstract
The synthesis of 2,2-dimethyl-1,3-dioxolane-4-methanol (solketal) from acetalization of glycerol with acetone was carried out over two types of ZSM-5 zeolites of similar Si/Al ratio (=12.5 and 13.5) characterized with different particle sizes. The reaction was performed in a liquid phase, under mild reaction conditions. The applied samples showed very different glycerol conversion depending on the particle size of the catalysts. Using large particle materials results in relatively low activity in the studied reaction due to the long diffusion way of substrates and products. The modification of commercial zeolites by means of grinding results in the formation of fine agglomerates and brings about a significant increase in solketal yield.
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Liu X, Ma H, Wu Y, Wang C, Yang M, Yan P, Welz-Biermann U (2011) Green Chem 13:697–701
Pariente S, Tanchoux N, Faula F (2008) Green Chem 11:1256–1261
Venugopal A, Sarkali R, Naveen Kumar S, Kotesh Kumar M, Syed John S, Kriszna Reddy J, Hari Padmasri A (2014) J Chem Sci 126:387–393
Konaka A, Tago T, Yoshikawa T, Nakamura A, Maruda T (2011) Res Chem Intermed 37:1247–1256
Zheng Y, Chen X, Shen Y (2008) Chem Rev 108:5253–5277
Rahmat N, Abdullah AZ, Mohamed AR (2010) Renew Sustain Energy Rev 14:987–1000
Guerrero-Pérez MO, Rosas JM, Bedia J, Rodríguez-Mirasol J, Cordero T (2009) Recent Pat Chem Eng 2:11–21
Ferreira P, Fonseca IM, Ramos AM, Vital J, Castanheiro JE (2010) Appl Catal B 98:94–98
Vicente G, Melero JA, Morales G, Paniagua M, Martín E (2010) Green Chem 12:899–907
Da Silva CXA, Gonçalves VLC, Mota CJA (2009) Green Chem 11:38–41
Deutsch J, Martin A, Lieske H (2007) J Catal 245:428–435
Gonçalves VLC, Pinto BP, Silva JC, Mota CJA (2008) Catal Today 673:133–135
De Torres M, Jiménez-osés G, Mayoral JA, Pires E, De los Santos M (2012) Fuel 94:614–616
Rodrigues R, Gonçalves M, Mandelli D, Pescarmona PP, Carvalho WA (2014) Catal Sci Technol 4:2293–2301
Serafim H, Fonseca IM, Ramos AM, Vital J, Castanheiro JE (2011) Chem Eng J 178:291–296
Manjunathan P, Paradur SP, Halgeri AB, Shanbhag GV (2015) J Mol Catal A 396:47–54
Jia C-J, Liu Y, Schmidt W, Lu A-H, Schüth F (2010) J Catal 269:71–79
Firoozi M, Baghalha M, Asadi M (2009) Catal Commun 10:1582–1585
Viswanadham N, Saxena SK, Kumar J, Sreenivasulu P, Nandan D (2012) Fuel 95:298–304
Konno H, Okamura T, Kawahara T, Nakasaka Y, Tago T, Masuda T (2012) Chem Eng J 207–208:490–496
Song W, Grassian VH, Larsen SC (2005) Chem Commun 23:2951–2953
Larsen SC (2007) J Phys Chem C 111:18464–18474
Kong C, Tsuru T (2010) Chem Eng Process 49:809–814
Gopalakrishnan S, Yada S, Muench J, Selvam T, Schwieger W, Sommer M, Peukert W (2007) Appl Catal A 327:132–138
López-Medina R, Sobczak I, Golinska-Mazwa H, Ziolek M, Bañares MA, Guerrero-Pérez MO (2012) Catal Today 187:195–200
Pieta IS, Ishaq M, Wells RPK, Anderson JA (2010) Appl Catal A 390:127–134
Khabtou S, Chevreau T, Lavalley JC (1994) Microporous Mater 3:133–148
Frisch MJ et al (2003) Gaussian 03, Revision B.01. Gaussian, Inc, Pittsburgh
Li L, Korányi TI, Sels BF, Pescarmona PP (2012) Green Chem 14:1611–1619
Akçay K, Sirkecioğlu A, Tatlıer M, Savaşçi ÖT, Erdem-Şenatalar A (2004) Powder Technol 142:121–128
Han W, Jia Y, Xiong G, Yang W (2007) Sci Technol Adv Mater 8:101–105
Davis TM, Chen C-Y, Žilková N, Vitvarová-Procházková D, Čejka J, Zones SI (2013) J Catal 298:84–93
Nair GS, Adrijanto E, Alsalme A, Kozhevnikov IV, Cooke DJ, Brown DR, Shiju NR (2012) Catal Sci Technol 2:1173–1179
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Kowalska-Kus, J., Held, A. & Nowinska, K. Enhancement of the catalytic activity of H-ZSM-5 zeolites for glycerol acetalization by mechanical grinding. Reac Kinet Mech Cat 117, 341–352 (2016). https://doi.org/10.1007/s11144-015-0922-4
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DOI: https://doi.org/10.1007/s11144-015-0922-4