Skip to main content

Kinetics and synergistic effect of iodide ion and naphthylamine for the inhibition of corrosion reaction of mild steel in hydrochloric acid

Abstract

The inhibition of mild steel corrosion in HCl solution by naphthylamine (NA), KI and the synergism of KI with NA was studied at different temperatures using weight loss and electrochemical techniques. Electrochemical techniques show that the NA–KI blend is a mixed-type inhibitor. The inhibition efficiency increases with an increase in inhibitor concentration but decreases with a rise in temperature. The adsorption followed the Freundlich isotherm with negative values of \(\Delta {\text{G}}_{\text{ads}}^{0}\), suggesting a stable, and spontaneous inhibition process. The maximum blend efficiency was 95 % at high level of concentration and low level of temperature.

This is a preview of subscription content, access via your institution.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9

References

  1. Ameer MA, Fekry AM (2010) Inhibition effect of newly synthesized heterocyclic organic molecules on corrosion of steel in alkaline medium containing chloride. Int J Hydrogen Energy 35:11387–11396

    CAS  Article  Google Scholar 

  2. Khadom AA, Yaro AS, Kadhum AH, AlTaie AS, Musa AY (2009) The effect of temperature and acid concentration on corrosion of low carbon steel in hydrochloric acid media. Am J Appl Sci 6:1403–1409

    CAS  Article  Google Scholar 

  3. Musa AY, Khadom AA, Kadhum AH (2010) Kinetic approach to mild steel corrosion inhibition by 4-amino-5-phenyl-4H-1, 2, 4-triazole-3-thiol. J Taiwan Inst Chem Eng 41:126–128

    CAS  Article  Google Scholar 

  4. Bammou L, Belkhaouda M, Salghi R, Benali O, Zarrouk A, Zarrok H, Hammouti B (2014) Corrosion inhibition of steel in sulfuric acidic solution by the chenopodium ambrosioides extracts. J Assoc Arab Univ Basic Appl Sci 16:83–90

    Google Scholar 

  5. Khadom AA, Yaro AS, Kadhum AA (2010) Adsorption mechanism of benzotriazole for corrosion inhibition of copper-nickel alloy in hydrochloric acid. J Chil Chem Soc 55:150–152

    CAS  Article  Google Scholar 

  6. Karthikaiselvi R, Subhashini S (2014) Study of adsorption properties and inhibition of mild steel corrosion in hydrochloric acid media by water soluble composite poly (vinyl alcohol-omethoxyaniline). J Assoc Arab Univ Basic Appl Sci 16:74–82

    Google Scholar 

  7. Quraishi MA, Sardar R (2002) Corrosion inhibition of mild steel in acid solutions by some aromatic oxadiazoles. Mater Chem Phys 78:425–431

    Article  Google Scholar 

  8. Anejjar A, Salghi R, Zarrouk A, Benali O, Zarrok H, Hammouti B, Ebenso EE (2014) Inhibition of carbon steel corrosion in 1 M HCl medium by potassium thiocyanate. J Assoc Arab Univ Basic Appl Sci 15:21–27

    Google Scholar 

  9. Hosseini M, Mertens SFL, Ghorbani M, Arshadi MR (2003) Asymmetrical Schiff bases as inhibitors of mild steel corrosion in sulphuric acid media. Mater Chem Phys 78:800–808

    CAS  Article  Google Scholar 

  10. Lagrenee M, Mernari B, Chaibi N, Traisnel M, Vezin H, Bentiss F (2001) Investigation of the inhibitive effect of substituted oxadiazoles on the corrosion of mild steel in HCl medium. Corros Sci 43:951–962

    CAS  Article  Google Scholar 

  11. Bentiss F, Traisnel M, Vezin H, Lagrenee M (2003) Linear resistance model of the inhibition mechanism of steel in HCl by triazole and oxadiazole derivatives: structure–activity correlations. Corros Sci 45:371–380

    Article  Google Scholar 

  12. Bentiss F, Traisnel M, Vezin H, Hildebrand HF, Lagrenee M (2004) 2,5-Bis(4- dimethylaminophenyl)-1,3,4-oxadiazole and 2,5-bis(4-dimethylaminophenyl)- 1,3,4-thiadiazole as corrosion inhibitors for mild steel in acidic media. Corros Sci 46(2004):2781–2792

    CAS  Article  Google Scholar 

  13. Yaro AS, Khadom AA, Ibraheem HF (2011) Peach juice as an anti-corrosion inhibitor of mild steel. Anti Corros Methods Mater 5:116–124

    Article  Google Scholar 

  14. Ramazan S (2010) Investigation of the inhibition effect of 5-((E)-4-phenylbuta-1,3-dienylideneamino) 1,3,4-thiadiazole-2-thiol Schiff base on mild steel corrosion in hydrochloric acid. Corros Sci 52:3321–3330

    Article  Google Scholar 

  15. Zarrok H, Zarrouk A, Hammouti B, Salghi R, Jama C, Bentiss F (2012) Corrosion control of carbon steel in phosphoric acid by purpald—Weight loss, electrochemical and XPS studies. Corros Sci 64:243–252

    CAS  Article  Google Scholar 

  16. Li Xianghong, Deng Shuduan, Hui Fu (2011) Synergistic inhibition effect of 6-benzylaminopurine and iodide ion on the corrosion of cold rolled steel in H3PO4 solution. Corros Sci 53:3704–3711

    CAS  Article  Google Scholar 

  17. Ebenso EE, Eddy NO, Odiongenyi AO (2009) Corrosion inhibition and adsorption properties of methocarbamol on mild steel in acidic medium. Port Electrochim Acta 27:13–22

    CAS  Article  Google Scholar 

  18. Oguzie EE (2007) Corrosion inhibition of aluminium in acidic and alkaline media by Sansevieria trifasciata extract. Corros Sci 49:1527–1539

    CAS  Article  Google Scholar 

  19. Umoren SA, Li Y, Wang FH (2010) Synergistic effect of iodide ion and polyacrylic acid on corrosion inhibition of iron in H2SO4 investigated by electrochemical techniques. Corros Sci 52:2422–2429

    CAS  Article  Google Scholar 

  20. Feng Y, Siowa KS, Teob WK, Hsieh AK (1999) The synergistic effects of propargyl alcohol and potassium iodide on the inhibition of mild steel in 9 M sulfuric acid solution. Corros Sci 30:718–741

    Google Scholar 

  21. Khadom AA, Yaro AS (2011) Protection of low carbon steel in phosphoric acid by potassium iodide. Prot Met Phys Chem Surf 47:662–669

    CAS  Article  Google Scholar 

  22. Abdel Nazeer A, Fouda AS, Ashour EA (2011) J Mater Environ Sci 2:24

    CAS  Google Scholar 

  23. Uddin MT, Islam MS, Abedin MZ (2007) Adsorption of phenol from aqueous solution by water hyacinth ash. ARPN J Eng Appl Sci 2(2):121–128

    Google Scholar 

  24. Unuabonah E, Olu-Owolabi B, Adebowale O, Ofomaja E (2007) Colloids Surf A Physicochem Eng Aspects 292:202

    CAS  Article  Google Scholar 

  25. Mohan S, Karthikeyan J (1997) Removal of lignin and tannin color from aqueous solution by adsorption on to activated carbon solution by adsorption on to activated charcoal. Environ Pollut 97:183–187

    CAS  Article  Google Scholar 

  26. El-Awady AA, Abd-El-Nabey BA, Aziz SG (1990) Int J Chem 1:169

    Google Scholar 

  27. Scendo M (2007) Corros Sci 49:3953

    CAS  Article  Google Scholar 

  28. Lente G, Fábián I, Poe AJ (2005) A common misconception about the Eyring equation. New J Chem 29:759

    CAS  Article  Google Scholar 

  29. Umoren A, Obot B, Ebenso E (2008) E-journal Chem. 5:355

    CAS  Article  Google Scholar 

  30. Ashassi-Sorkhabi H, Shaabani B, Seifzadeh D (2005) Appl Surf Sci 239:154

    CAS  Article  Google Scholar 

  31. Osman MM, El-Ghazawy RA, Al-Sabagh AM (2003) Mater Chem Phys 80:55

    CAS  Article  Google Scholar 

  32. Mansfeld F (1987) Corrosion mechanism. Marcel Dekkar, New York, p 119

    Google Scholar 

  33. Li Xianghong, Deng Shuduan, Guannan Mu, Hui Fu, Yang Fazhong (2008) Inhibition effect of nonionic surfactant on the corrosion of cold rolled steel in hydrochloric acid. Corros Sci 50:420–430

    CAS  Article  Google Scholar 

  34. Singh AK, Quraishi MA (2010) Effect of Cefazolin on the corrosion of mild steel in HCl solution. Corros Sci 52:152–160

    CAS  Article  Google Scholar 

  35. Sahin M, Bilgic S, Yilmaz H (2002) The inhibition effects of some cyclic nitrogen compounds on the corrosion of the steel in NaCl mediums. Appl Surf Sci 195:1–7

    CAS  Article  Google Scholar 

  36. Khaled KF, Babić-Samardžija K, Hackerman N (2005) Theoretical study of the structural effects of polymethylene amines on corrosion inhibition of iron in acid solutions. Electrochim Acta 50:2515–2520

    CAS  Article  Google Scholar 

  37. Ridhwan AM, Rahim AA, Shah AM (2012) Synergistic effect of halide ions on the corrosion inhibition of mild steel in hydrochloric acid using mangrove tannin. Int J Electrochem Sci 7:8091–8104

    CAS  Google Scholar 

  38. Umoren SA, Eduok UM, Oguzie EE (2008) Corrosion inhibition of mild steel in 1 M H2SO4 by polyvinyl pyrrolidone and synergistic iodide additives. Port Electrochim Acta 26:533–546

    CAS  Article  Google Scholar 

  39. Ahmed MJ, Khadom AA, Kadhum AH (2009) Optimization hydrogenation process of d-glucose to D-sorbitol over Raney nickel catalyst. Eur J Sci Res 30:294–304

    Google Scholar 

  40. Musa AY, Kadhum AA, Mohamad AB, Daud AR, Takriff MS, Kamarudin SK (2009) A comparative study of the corrosion inhibition of mild steel in sulphuric acid by 4,4-dimethyloxazolidine-2-thione. Corros Sci 51:2393–2399

    CAS  Article  Google Scholar 

  41. Shams El Din AM, Mohammed RA, Haggag HH (1997) Corrosion inhibition by molybdate/polymaliate mixtures. Desalination 114:85–95

    CAS  Article  Google Scholar 

  42. De Souza FS (2009) Caffeic acid as a green corrosion inhibitor for mild steel. Corros Sci 51:642–649

    Article  Google Scholar 

  43. Ashassi-Sorkhabi H, Majidi MR, Seyyedi K (2004) Investigation of inhibition effect of some amino acids against steel corrosion in HCl solution. Appl Surf Sci 225:176–185

    CAS  Article  Google Scholar 

  44. Abboud Y, Abourriche A, Saffaj T, Berrada M, Charrouf M (2006) The inhibition of mild steel corrosion in acidic medium by 2,2′-bis(benzimidazole). Appl Surf Sci 252(23):8178–8184

    CAS  Article  Google Scholar 

  45. Fawcett WR, Kovacova Z, Motheo A, Foss C (1992) Application of the AC admittance technique to double-layer studies on polycrystalline gold electrodes. J Electroanal Chem 326:91–103

    CAS  Article  Google Scholar 

  46. Khaled K, Hackerman FN (2003) Investigation of the inhibitive effect of ortho-substituted anilines on corrosion of iron in 1 M HCl solutions. Electrochim Acta 48:2715–2723

    CAS  Article  Google Scholar 

  47. Migahed MA (2005) Electrochemical investigation of the corrosion behaviour of mild steel in 2 M HCl solution in presence of 1-dodecyl-4-methoxy pyridinium bromide. Mater Chem Phys 93:48–53

    CAS  Article  Google Scholar 

  48. Cang H, Fei Z, Shi W, Xu Q (2012) Experimental and theoretical study for corrosion inhibition of mild steel by l-cysteine. Int J Electrochem Sci 7:10121–10131

    CAS  Google Scholar 

  49. Martinez S, Metikos-Hukovic M (2003) A nonlinear kinetic model introduced for the corrosion inhibitive properties of some organic inhibitors. J Appl Electrochem 33:1137–1142

    CAS  Article  Google Scholar 

  50. Prathibha BS, Kotteeswaran P, Bheema Raju V (2012) Study on the inhibition of mild steel corrosion by N, N-dimethyl-N-(2-phenoxyethyl) dodecan-1-aminiumbromide in HCl medium. IOSR J Appl Chem 2:61–70

    Article  Google Scholar 

  51. Damaskin BB, Petrii OA, Batraktov B (1971) Adsorption of organic compounds on electrodes. Plenum Press, New York

    Book  Google Scholar 

  52. Amina MA, Mohsenb Q, Hazzazi OA (2009) Synergistic effect of I ions on the corrosion inhibition of Al in 1.0 M phosphoric acid solutions by purine. Mater Chem Phys 114:908–914

    Article  Google Scholar 

  53. Lukomska A, Sobkowski J (2004) Potential of zero charge of monocrystalline copper electrodes in perchlorate solutions. J Electroanal Chem 567:95–102

    CAS  Article  Google Scholar 

  54. Amin MA, Abd Sayed S, El-Rehim EE, El-Sherbini F, Bayoumi Rady S (2007) The inhibition of low carbon steel corrosion in hydrochloric acid solutions by succinic acid: Part I. Weight loss, polarization, EIS, PZC, EDX and SEM studies. Electrochim Acta 52:3588–3600

    CAS  Article  Google Scholar 

  55. Ashish KS, Sudhish KS, Ebenso EE (2011) Cefacetrile as corrosion inhibitor for mild steel in acidic media. Int J Electrochem Sci 6:5689–5700

    Google Scholar 

  56. Kortum G (1965) Treatise on electrochemistry, 2nd edn. Elsevier Publishing Co., New York

    Google Scholar 

  57. Yaro AS, Khadom AA, Lahmod SM (2013) Kinetics of the corrosion inhibition reaction of steel alloys in acidic media by potassium iodide. Reac Kinet Mech Cat 109:417–432

    CAS  Article  Google Scholar 

Download references

Acknowledgments

Special thanks to Prof. Dr. Abdul Amir H. Kadhum—National University of Malaysia, Department of Processes and Chemical Engineering for his continuous support.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Anees A. Khadom.

Rights and permissions

Reprints and Permissions

About this article

Verify currency and authenticity via CrossMark

Cite this article

Khadom, A.A. Kinetics and synergistic effect of iodide ion and naphthylamine for the inhibition of corrosion reaction of mild steel in hydrochloric acid. Reac Kinet Mech Cat 115, 463–481 (2015). https://doi.org/10.1007/s11144-015-0873-9

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11144-015-0873-9

Keywords

  • Corrosion
  • Modeling
  • Inhibitor
  • Mild steel
  • Synergistic
  • Adsorption