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Bulk and surface characterization and isomerization activity of Pt/WO4 2−/ZrO2 catalysts of different preparations

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Abstract

The texture, phase and surface composition and acidity of impregnated and precipitated Pt/WO4 2−/ZrO2 catalysts have been investigated with XRD, XPS, FTIR spectroscopy, and BET measurements. It has been shown that increasing the tungstate ion concentration in hydrated zirconium oxide results in an increase in the t-ZrO2 fraction in the catalysts following high temperature activation. While a fraction of W6+ and W5+ cations forms a solid solution with zirconia, the remaining W ions are stabilized on the catalysts surface as (–WOx–)n clusters. The catalytic activity in n-heptane isomerization seems to correlate with catalyst surface acidity to reach the greatest value at the WO4 2− concentration in the range of 12.9–17.6 mol %.

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Acknowledgments

The authors thank Evgeniy A Paukshtis of Boreskov Institute of Catalysis SB RAS for assistance in research by IR spectroscopy and useful discussions.

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Authors and Affiliations

  1. Institute of Chemistry and Chemical Technology SB RAS, 50-24 Akademgorodok, Krasnoyarsk, 660036, Russia

    Peter N. Kuznetsov, Anastasia V. Kazbanova, Ludmila I. Kuznetsova, Vladimir I. Kovalchuk & Yuriy L. Mikhlin

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  1. Peter N. Kuznetsov
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  2. Anastasia V. Kazbanova
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  3. Ludmila I. Kuznetsova
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  4. Vladimir I. Kovalchuk
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  5. Yuriy L. Mikhlin
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Correspondence to Peter N. Kuznetsov.

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Kuznetsov, P.N., Kazbanova, A.V., Kuznetsova, L.I. et al. Bulk and surface characterization and isomerization activity of Pt/WO4 2−/ZrO2 catalysts of different preparations. Reac Kinet Mech Cat 113, 69–84 (2014). https://doi.org/10.1007/s11144-014-0755-6

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  • DOI: https://doi.org/10.1007/s11144-014-0755-6

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