Abstract
A series of 10 wt% Ni2P/SiO2 catalysts with cesium loading from 0 to 7.5 wt% were prepared by means of temperature-programmed reduction, and the effects of the cesium addition on the catalytic properties of the Ni2P/SiO2 catalyst for isobutane dehydrogenation have been investigated by reaction tests and some physicochemical characterizations such as TEM, XRD, H2-TPR, XPS, H2-TPD, NH3-TPD. It was found that cesium exists as CsOH on the catalyst surface, which partly covers the Ni2P surface or boundaries between Ni2P and SiO2 to decrease the acid strength and acid site number. XPS analysis suggests that Cs acts as an electronic promoter to Ni2P phase. The 6.5 wt% Cs-containing Ni2P/SiO2 catalyst showed the best catalytic performance and stability. After reaction for 4 h, selectivity toward isobutene of higher than 96 % was achieved with the corresponding conversion value of about 6.0 % at 733 K. The enhancement in the catalytic selectivity and stability of the Cs promoted catalysts is attributed to the decrease in acid strength and acid site number and the electrons transfer from Cs to Ni.
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Minh CL, Alanazi AK, Miron DJ, Brown TC (2012) Catal Lett 142:1470–1473
Ding JF, Shao R, Wu J, Qin ZF, Wang JG (2010) React Kinet Mech Cat 101:173–181
Ogonowski J, Skrzynska E (2008) Catal Lett 121:234–240
Airaksinen SMK, Krause AOI (2005) Ind Eng Chem Res 44:3862–3868
Tasbihi M, Feyzi F, Amlashi MA, Abdullah AZ (2007) Fuel Process Technol 88:883–889
Siri GJ, Bertolini GR, Casella ML, Ferretti OA (2005) Mater Lett 59:2319–2324
Zangeneh FT, Sahebdelfar S, Bahmani M (2005) Chin J Chem Eng 21(7):730–735
Zhang YW, Zhou YM, Sheng XL, Wan LH, Li YJ, Xiao YM, Yu B, Zeng Z (2012) Fuel Process Technol 104:23–30
Sun GS, Huang QZ, Li HQ, Liu HT, Zhang Z (2011) Chin J Catal 32(8):1424–1429
Zhao HH, Song HL, Xu LL, Chou L (2013) J Appl Catal A 456:188–196
Zhao HH, Song HL, Chou LJ (2013) Microporous Mesoporous Mater 181:182–191
Fu YH, Ma HC, Wang ZL, Wu TH, Wang GJ (2004) J Mol Catal A 21:163–168
Yusaku T, Xia Q, Akihide T, Hiroyasu N, Katsutoshi N (2005) Appl Catal A 296:63–69
Takita Y, Sano KI, Muraya T, Nishiguchi H, Kawata N (1998) Appl Catal A 170:23–31
Duan YZ, Zhou YM, Zhang YW, Sheng XL (2011) Catal Lett 141:120–127
Oyama ST (2003) J Catal 216(1–2):343–352
Xie Y, Su HL, Qian XF, Liu XM, Qian YT (2000) J Solid State Chem 149(1):88–91
Prins R, Pirngruber G, Weber T (2001) Chimia 55:791–795
Liao H, Xu XL, Chen WQ, Shi QJ (2012) Acta Phys-Chim Sin 28:2924–2930
Sawhil SJ, Layman KA, Van Wyk DR, Engelhard MH, Wang CM (2005) J Catal 231(2):300–313
Duan XP, Li X, Wang AJ, Teng Y, Wang Y, Hu YK (2010) Catal Today 149:11–18
Hensen EJM, De Beer VHJ, Van Veen JAR, Van Santen RAA (2002) Catal Lett 84:59–67
Hj Martin, Pham DK, Brorson M, Madler L, Jensen AD, Grunwaldt JD (2013) Catal Lett 143:386–394
Kim SB, Choi MJ, Park DC, Lee KW (1991) Korean J Chem Eng 8(3):137–142
Oyama ST, Wang XG, Requejo F, Sato T, Yoshimura Y (2002) J Catal 209:1–5
Moriceau PB, Pennequin A, Grzybowska B, Barbaux Y (2003) Appl Catal A 245:55–67
Moriceau P, Grzybowska B, Barbaux Y (1998) Pol J Chem 72:910–915
Zangeneh FT, Sahebdelfar S (2011) Iranian J Chem Eng 8:48–54
Sun M, Zhang JZ, Cao CJ, Zhang QH, Wang Y, Wan HL (2008) Appl Catal A 349:212–221
Murata S, Aika KL (1992) J Catal 136:110–117
Murata S, Aika KL (1992) J Catal 136:118–125
Briggs D, Seah MP (eds) (1983) Practical surface analysis by auger and X-ray photoelectron spectroscopy. Wiley, New York
Sawhill SJ, Layman KA, Van Wyk DR, Engelhard MH, Wang ChM, Bussell ME (2005) J Catal 231:300–313
Liu XG, Chen JX, Zhang JY (2008) Ind Eng Chem Res 47:5362–5368
Sun LM, Chen JX, Wang RJ (2009) Catal Lett 133(3–4):346–353
Dry ME, Shingles T, Boshoff LJ, Oosthuizen GJ (1969) J Catal 15:190–199
Panagiotopoulou P, Kondarides DI (2008) J Catal 260:141–149
Chen JX, Zhou SJ, Ci DH, Zhang JX, Wang RJ (2009) Ind Eng Chem Res 48:3812–3819
Aika K, Kumasaka M, Oma T, Kato O, Matsuda H, Watanabe N, Yamazaki K (1986) Appl Catal 28:57–68
Oyama ST, Wang X, Lee YK, Bando K, Requejo FG (2002) J Catal 210:207–217
Rodrigues VDO, Guillaume JE, Arnaldo CF (2010) J Phy Chem C 114:4557–4567
Jing FL, Katryniok B, Richard EB, Sebastien P (2013) Catal Today 203:32–39
Maia AJ, Oliveira BG, Esteves PM, Louis B, Lam YL, Pereira MM (2011) Appl Catal A 403:58–64
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We gratefully acknowledge the financial supports from the National Natural Science Foundation of China (No. 21276190 and 20806059).
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Xu, Y., Wang, X. & Lv, R. Interaction between Cs and Ni2P/SiO2 for enhancing isobutane dehydrogenation in the presence of hydrogen. Reac Kinet Mech Cat 113, 393–406 (2014). https://doi.org/10.1007/s11144-014-0738-7
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DOI: https://doi.org/10.1007/s11144-014-0738-7