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Mn-grafted imine-functionalized mesoporous SBA-15 as an efficient catalyst for Knoevenagel condensation under mild conditions

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Abstract

Surface functionalization of SBA-15 followed by its reaction with manganese acetate has been carried out to develop a new Mn-grafted functionalized mesoporous material and it was characterized by powder X-ray diffraction (XRD), BET nitrogen adsorption–desorption, IR spectroscopy, transmission electron microscopy and diffuse reflectance UV–Vis spectroscopy. The XRD and TEM analyses showed that textural properties of SBA-15 were retained during the grafting procedure and after five-time recycling. The resulting material was successfully applied as a heterogeneous catalyst for Knoevenagel condensation in good to excellent yields under mild conditions.

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Acknowledgments

The authors are grateful to University of Birjand research council for partial financial support of this work.

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Authors and Affiliations

  1. Nanochemistry Research Laboratory, Department of Chemistry, University of Birjand, PO Box 97175-615, Birjand, Iran

    Hesamaldin Mahmoudi & Reihaneh Malakooti

Authors
  1. Hesamaldin Mahmoudi
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  2. Reihaneh Malakooti
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Correspondence to Reihaneh Malakooti.

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Mahmoudi, H., Malakooti, R. Mn-grafted imine-functionalized mesoporous SBA-15 as an efficient catalyst for Knoevenagel condensation under mild conditions. Reac Kinet Mech Cat 113, 241–255 (2014). https://doi.org/10.1007/s11144-014-0722-2

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  • DOI: https://doi.org/10.1007/s11144-014-0722-2

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