Skip to main content
SpringerLink
Log in

Selective hydrocarbon production by the hydrocracking of glucose

  • Published:
Reaction Kinetics, Mechanisms and Catalysis Aims and scope Submit manuscript

Abstract

Re-modified Pt/SiO2–Al2O3 catalysts, which were active for the direct hydrotreating of jatropha oil into C18 hydrocarbons, were found to be effective for glucose transformation into C6 alkanes. At 350 °C and glucose/catalyst weight ratio of 2, the highest glucose conversion of 100 % was achieved with selectivity to C6 alkanes of 57.1 %. The reaction pathway involves glucose hydrocracking to form C6 polyols, followed by deoxyhydration and subsequent C=C bond hydrogenation by synergistic effect of Pt and Re.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4

Similar content being viewed by others

References

  1. Pan J, Li J, Wang C, Yang Z (2007) Reac Kinet Catal Lett 90(2):233

    Article  CAS  Google Scholar 

  2. Schimpf S, Louis C, Claus P (2007) Appl Catal A 318:45

    Article  CAS  Google Scholar 

  3. Liang G, Cheng H, Li W, He L, Yu Y, Zhao F (2012) Green Chem 14(8):2146

    Article  CAS  Google Scholar 

  4. Karski S, Paryjczak T, Witoñska I (2003) Kinet Catal 44(5):618

    Article  CAS  Google Scholar 

  5. Murata K, Liu Y, Inaba M, Takahara I (2010) Catal Lett 140:8

    Article  CAS  Google Scholar 

  6. Murata K, Takahara I, Inaba M (2008) Reac Kinet Mech Cat 93:59

    Article  CAS  Google Scholar 

  7. D’Ippolito SA, Vera CR, Epron F, Samoila P, Especel C, Marécot P, Gutierrez LB, Pieck CL (2009) Ind Eng Chem Res 48:3771

    Article  Google Scholar 

  8. Vicerich MA, Especel C, Benitez VM, Epron F, Pieck CL (2011) Appl Catal A 407:49

    Article  CAS  Google Scholar 

  9. Kim H-D, Park HJ, Kim T-W, Jeong K-E, Chae H-J, Jeong S-Y, Lee C-H, Kim C-U (2012) Catal Today 185:73

    Article  CAS  Google Scholar 

  10. Kunkes EL, Simonetti DA, West RM, Serrano-Ruiz JC, Gartner CA, Dumesic JA (2008) Science 322:417

    Article  CAS  Google Scholar 

  11. Murata K, Liu Y, Inaba M, Takahara I (2010) Energy Fuels 24:2404

    Article  CAS  Google Scholar 

  12. Guedes AS, Fontaine C, Bouchy C, Brunet S (2010) Appl Catal B 100:165

    Article  CAS  Google Scholar 

  13. Sànchez MA, Mazzieri VA, Grau JM, Yori JC, Pieck CL (2011) J Chem Technol Biotechnol 86:1198

    Article  Google Scholar 

  14. Guryev YV, Ivanova II, Lunin VV, Grünert W, van den Berg MWE (2007) Appl Catal A 329:16

    Article  CAS  Google Scholar 

  15. Kobayashi H, Ito Y, Komanoya T, Hosaka Y, Dhepe PL, Kasai K, Hara K, Fukuoka A (2011) Green Chem 13:326

    Article  CAS  Google Scholar 

  16. Shiramizu M, Toste FD (2012) Angew Chem Int Ed 51:8082

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. National Institute of Advanced Industrial Science and Technology, AIST Tsukuba Central 5, 1-1-1, Higashi, Tsukuba, Ibaraki, 305-8565, Japan

    Kazuhisa Murata, Megumu Inaba, Isao Takahara & Yanyong Liu

Authors
  1. Kazuhisa Murata
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Megumu Inaba
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Isao Takahara
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Yanyong Liu
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Kazuhisa Murata.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Murata, K., Inaba, M., Takahara, I. et al. Selective hydrocarbon production by the hydrocracking of glucose. Reac Kinet Mech Cat 110, 295–307 (2013). https://doi.org/10.1007/s11144-013-0619-5

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11144-013-0619-5

Keywords

Search

Navigation