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Transition metal (Fe, Co) and organic silanol modified mesoporous titanium phosphates as catalysts for the oxidation of benzyl alcohol in water

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Abstract

Transition metal (Fe, Co) and organic silanol modified mesoporous titanium phosphates were synthesized using the surfactant templating process and evaluated by the selective oxidation of benzyl alcohol with H2O2 in water. All the materials were characterized by FT-IR, powder X-ray diffraction, scanning electron micrograph studies, UV–Vis and TG–DTA. The effects of the surface hydrophobicity and transition metal incorporation on the catalytic performance of MTP were investigated. Among these catalysts, Fe-MTP showed the highest catalytic activity under mild conditions without any organic solvent, giving 80.5 % of benzyl alcohol conversion and 96.4 % of benzaldehyde selectivity.

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Acknowledgments

The authors gratefully acknowledge financial support from National Natural Science Foundation of China (No. 51076042), Scientific Research Fund of Hunan Provincial Education Department (No. 10C0674), Scientific Research Fund of Hunan Provincial Education Department (No. 08C323) and Scientific Research Fund of Hunan Provincial Science & Technology Department (No. 2011SK3123).

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Authors and Affiliations

  1. Department of Chemistry & Chemical Engineering, Hunan University of Science & Technology, Xiangtan, 411201, China

    Lijuan Chen

  2. Key Laboratory of Theoretical Chemistry and Molecular Simulating, Hunan Province and Ministry of Education, Xiangtan, 411201, China

    Lijuan Chen

  3. School of Energy and Safe, Hunan University of Science & Technology, Xiangtan, 411201, China

    Tao Feng & Pengfei Wang

  4. School of Life Science, Hunan University of Science & Technology, Xiangtan, 411201, China

    Yujun Xiang

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  1. Lijuan Chen
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  2. Tao Feng
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  3. Pengfei Wang
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Correspondence to Lijuan Chen.

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Chen, L., Feng, T., Wang, P. et al. Transition metal (Fe, Co) and organic silanol modified mesoporous titanium phosphates as catalysts for the oxidation of benzyl alcohol in water. Reac Kinet Mech Cat 110, 485–496 (2013). https://doi.org/10.1007/s11144-013-0606-x

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  • DOI: https://doi.org/10.1007/s11144-013-0606-x

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