Skip to main content
SpringerLink
Log in

Selective hydrogenation of cinnamaldehyde over ZSM-5 supported Co catalysts

  • Published:
Reaction Kinetics, Mechanisms and Catalysis Aims and scope Submit manuscript

Abstract

ZSM-5 supported Co catalysts were synthesized for the selective reduction of cinnamaldehyde (CMA) to the corresponding cinnamyl alcohol (CMO). The effects of the support (ratio of Si/Al of ZSM-5), catalysts pre-treatment (calcination) and catalyst amount on the conversion of CMA and selectivity to CMO were studied. The results showed that a lower ratio of Si/Al showed higher activity and the catalyst exhibited the highest yield of CMO when the ratio of Si/Al for ZSM-5 was 25. The conversion of CMA increased with the increase of catalyst amount. The reaction results showed that the highest activity occurred when the calcination temperature was 873 K, and the optimum CMO yield was obtained from the catalyst calcined at 773 K. The optimum CMO yield (61.9 %) obtained from Co/ZSM-5(25) catalyst (0.6 g) after reaction for 6 h.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5

Similar content being viewed by others

References

  1. Gallezot P, Richard D (1998) Catal Rev Eng 40:81

    Article  CAS  Google Scholar 

  2. Kijenski J, Winiarek P (2000) Appl Catal A 193:1

    Article  Google Scholar 

  3. Kluson P, Cerveny L (1995) Appl Catal A 128:13

    Article  CAS  Google Scholar 

  4. Blackmond D, Oukaci R, Blanc B et al (1991) J Catal 131:401

    Article  CAS  Google Scholar 

  5. Galvagno S, Capannelli G, Neri G et al (1991) J Mol Catal 64:237

    Article  CAS  Google Scholar 

  6. daSilva AB, Jordao E, Mendes MJ et al (1998) J Chem Eng 15:140

    CAS  Google Scholar 

  7. Schroder U, Verdier L (1993) J Catal 142:490

    Article  Google Scholar 

  8. Bonaccorsi L, Mercadante L, Galvagno S (1997) Ind Eng Chem Res 36:3554

    Article  Google Scholar 

  9. Coq B, Figueras F, Geneste P et al (1993) J Mol Catal 78:211

    Article  CAS  Google Scholar 

  10. Kaspar J, Grazianic M, Escobar GP et al (1992) J Mol Catal 72:243

    Article  CAS  Google Scholar 

  11. Coq B, Figueras F, Moreau C et al (1993) Catal Lett 22:189

    Article  CAS  Google Scholar 

  12. Neri G, Mercandante L, Milone C et al (1996) J Mol Catal 108:41

    Article  CAS  Google Scholar 

  13. Plomp AJ, van Asten DMP, van der Eerden AMJ et al (2009) J Catal 263:146

    Article  CAS  Google Scholar 

  14. Merlo AB, Machado BF, Vetere V et al (2010) Appl Catal A 383:43

    Article  CAS  Google Scholar 

  15. Arai M, Takahashi H, Shirai M et al (1999) Appl Catal A 176:229

    Article  CAS  Google Scholar 

  16. Li GJ, Li T, Xu YD et al (1997) Guo. Stud Surf Sci Catal 105B:1203

    Article  CAS  Google Scholar 

  17. Handjani S, Marceau E, Blanchard J, et al (2011) J Catal 282(1):228–236

  18. Chatterjee M, Ikushima Y, Yokoyama T et al (2009) Microporous Mesoporous Mater 117:201

    Article  CAS  Google Scholar 

  19. Hajek J, Kumar N, Salmi T et al (2005) Catal Today 100:349

    Article  CAS  Google Scholar 

  20. Hajek J, Kumar N, Nieminena V et al (2004) Chem Eng J 103:35

    Article  CAS  Google Scholar 

  21. Han XX, Zhou RX, Zheng XM (2006) Ind J Chem Sect A 45:1646

    Google Scholar 

  22. Liu YX, Li QG, Yan W (2009) CIESC J 60:98

    CAS  Google Scholar 

  23. Chen XF, Li HX, Dai WL, Wang J, Ran Y, Qiao MH (2003) Appl Catal A 253:359

    Article  CAS  Google Scholar 

Download references

Acknowledgments

The work was supported by Zhejiang Province Science and Technology Project (2009C31085) and Excellent Young Teachers funding schemes of Zhejiang Province.

Author information

Authors and Affiliations

  1. Zhejiang Pharmaceutical College, Ningbo, 315000, Zhejiang, China

    Bin Zhang, Xin Bo Zhang, Li Yong Xu, Ya Juan Zhang, Yong Hua Qin & Ci Fu Liang

Authors
  1. Bin Zhang
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Xin Bo Zhang
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Li Yong Xu
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Ya Juan Zhang
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Yong Hua Qin
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Ci Fu Liang
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Xin Bo Zhang.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Zhang, B., Zhang, X.B., Xu, L.Y. et al. Selective hydrogenation of cinnamaldehyde over ZSM-5 supported Co catalysts. Reac Kinet Mech Cat 110, 207–214 (2013). https://doi.org/10.1007/s11144-013-0589-7

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11144-013-0589-7

Keywords

Search

Navigation