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Kinetics of the reaction of OH radicals with CH3OH and CD3OD studied by laser photolysis coupled to high repetition rate laser induced fluorescence

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Abstract

A new experimental set-up coupling laser photolysis to a 10 kHz dye laser as the excitation source for OH fluorescence has been validated by measuring the rate constant of the reaction CH3OH + OH. The rate constant of the deuterated homologue CD3OD + OH has been measured under the same conditions.

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Authors and Affiliations

  1. Laboratoire de Physico-Chimie des Processus de Combustion et de l’Atmosphère — CNRS UMR 8522, Université des Sciences et Technologies de Lille, Villeneuve d’Ascq, France

    Alexander Parker, Chaithanya Jain, Coralie Schoemaecker & Christa Fittschen

Authors
  1. Alexander Parker
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  2. Chaithanya Jain
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  3. Coralie Schoemaecker
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  4. Christa Fittschen
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Correspondence to Christa Fittschen.

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Parker, A., Jain, C., Schoemaecker, C. et al. Kinetics of the reaction of OH radicals with CH3OH and CD3OD studied by laser photolysis coupled to high repetition rate laser induced fluorescence. React Kinet Catal Lett 96, 291–297 (2009). https://doi.org/10.1007/s11144-009-5509-5

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  • DOI: https://doi.org/10.1007/s11144-009-5509-5

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