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Primary kinetic isotope effect in the nitrosation of 1,3- dialkylureas

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Abstract

In the nitrosation mechanism of 1,3 dialkylureas, the existence of protonic transfer to the solvent as a rate-limiting step was confirmed when a primary kinetic isotope effect was observed in these reactions.

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Authors and Affiliations

  1. Instituto Tecnológico de Celaya, Av. Tecnológico y García Cubas S/N Celaya Guanajuato, México CP, 38010, México

    Guillermo González-Alatorre, Daniel Pérez-Méndez, Andrés Godínez-García, Eleazar M. Escamilla-Silva & Vicente Rico-Ramírez

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  1. Guillermo González-Alatorre
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  2. Daniel Pérez-Méndez
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  3. Andrés Godínez-García
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  4. Eleazar M. Escamilla-Silva
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  5. Vicente Rico-Ramírez
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Correspondence to Guillermo González-Alatorre.

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González-Alatorre, G., Pérez-Méndez, D., Godínez-García, A. et al. Primary kinetic isotope effect in the nitrosation of 1,3- dialkylureas. React Kinet Catal Lett 96, 5–12 (2009). https://doi.org/10.1007/s11144-009-5398-7

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  • DOI: https://doi.org/10.1007/s11144-009-5398-7

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