Skip to main content
SpringerLink
Log in

Ruthenium complex immobilization on layered silicate materials

  • Published:
Reaction Kinetics, Mechanisms and Catalysis Aims and scope Submit manuscript

Abstract

In this work, hydrogenation of sorbic acid to cis-hex-3-enoic acid using homogeneous Ru catalyst [Cp*Ru(sorbic acid)]Tf (Tf = CF3SO3 −) immobilized to smectite materials by means of ion exchange has been studied. The immobilized catalyst was utilized for heterogeneous hydrogenation of sorbic acid to the desired cis-hex-3-enoic acid, achieving the selectivity of up to 95% and the possibility of the catalyst to be reused.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2

Similar content being viewed by others

References

  1. Steines S, Englert U, Driessen-Hoelscher B (2000) Chem Commun 3:217

    Article  Google Scholar 

  2. Driessen-Hoelscher B (2002) Synth Methods Organomet Inorg Chem 10:94

    Google Scholar 

  3. Niessen HG, Schleyer D, Wiemann S, Bargon J, Steines S, Driessen-Hoelscher B (2000) Magn Res Chem 38:747

    Article  CAS  Google Scholar 

  4. Leitmannová E, Storch J, Červený L (2006) React Kinet Catal Lett 88:11

    Article  Google Scholar 

  5. Leitmannová E, Červený L (2007) J Mol Catal A 261:242

    Article  Google Scholar 

  6. Pinnavaia T (1983) Science 220:4595

    Article  Google Scholar 

  7. Pinnavaia T, Raythatha R, Lee J, Halloran LJ, Hoffmann FF (1979) J Am Chem Soc 101:6891

    Article  CAS  Google Scholar 

  8. Raythatha R, Pinnavaia T (1981) J Organomet Chem 218:115

    Article  CAS  Google Scholar 

  9. Quayle WH, Pinnavaia TJ (1979) Inorg Chem 18:2840

    Article  CAS  Google Scholar 

  10. Mazzei M, Marconi W, Riocci M (1980) J Mol Catal 9:381

    Article  CAS  Google Scholar 

  11. Claver C, Fernandez E, Margalef-Catala R, Medina F, Salagre P, Sueiras JE (2001) J Catal 201:70

    Article  CAS  Google Scholar 

  12. Simons Ch, Hanefeld U, Arends IWCE, Sheldon RA, Maschmeyer T (2004) Chem Eur J 10:5829

    Article  CAS  Google Scholar 

  13. Simons Ch, Hanefeld U, Arends IWCE, Minnard AJ, Maschmeyer T, Sheldon RA (2004) Chem Commun 2830

  14. Kirchhoff J, Fries G, Driessen-Hoelscher B, Kalz W, Nobis M (2004) EP 1394170 CAN 140:217811

    Google Scholar 

Download references

Acknowledgements

Authors wish to acknowledge Ministry of Education of the Czech Republic for the financial support of this research (Grant No. MSM 6046137301).

Author information

Authors and Affiliations

  1. Department of Organic Technology, Institute of Chemical Technology, Technicka 5, 166 28, Prague 6, Czech Republic

    Eliška Leitmannová & Libor Červený

Authors
  1. Eliška Leitmannová
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Libor Červený
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Libor Červený.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Leitmannová, E., Červený, L. Ruthenium complex immobilization on layered silicate materials. Reac Kinet Mech Cat 99, 79–84 (2010). https://doi.org/10.1007/s11144-009-0105-2

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11144-009-0105-2

Keywords

Search

Navigation