Skip to main content
SpringerLink
Log in

Mathematical modeling of toluene oxidation with a periodic reactor operation

  • Published:
Reaction Kinetics, Mechanisms and Catalysis Aims and scope Submit manuscript

Abstract

Mathematical modeling of toluene oxidation under unsteady state catalyst created by forced oscillations of concentration of toluene in the reactor inlet was carried out. It is shown that, under periodic reactor operation, the benzaldehyde yield was up to several times higher than the steady state value. This was explained by the participation of different oxygen species in the partial and total oxidation on the catalyst surface.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4

Similar content being viewed by others

References

  1. Ivanov EA, Reshetnikov CI, Ivanov AA (1999) React Kinet Catal Lett 66:47

    Article  CAS  Google Scholar 

  2. Contractor RM, Sleight AW (1988) Catal Today 3:175

    Article  CAS  Google Scholar 

  3. Silveston P, Ross RR, Renken A (1995) Catal Today 25:91

    Article  CAS  Google Scholar 

  4. Ivanov EA, Reshetnikov SI, Bulushev DA (2004) React Kinet Catal Lett 82:199

    Article  CAS  Google Scholar 

  5. Bond GL (1997) Appl Catal A: Gen 157:91

    Article  CAS  Google Scholar 

  6. Bulushev DA, Rainone F, Kiwi-Minsker L, Renken A (2001) Langmuir 17:5276

    Article  CAS  Google Scholar 

  7. Bulushev DA, Kiwi-Minsker L, Renken A (2000) Catal Today 61:271

    Article  CAS  Google Scholar 

Download references

Acknowledgment

The authors acknowledge the financial support of RFBR (Grant No 09-03-90406-Ukr_f_a) for the financial support.

Author information

Authors and Affiliations

  1. Boreskov Institute of Catalysis, 630090, Novosibirsk, Russia

    S. I. Reshetnikov

Authors
  1. S. I. Reshetnikov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to S. I. Reshetnikov.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Reshetnikov, S.I. Mathematical modeling of toluene oxidation with a periodic reactor operation. Reac Kinet Mech Cat 99, 23–28 (2010). https://doi.org/10.1007/s11144-009-0097-y

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11144-009-0097-y

Keywords

Search

Navigation