Abstract
Oxidative bromination of ethylene was found to proceed effectively in the presence of a catalytic system Pd(OAc)2–LiNO3 in two-component BMImBr–HOAc and three-component BMImBr–HOAc–H2O solvents. At a large content of BMImBr, conversion of ethylene was found to yield 1,2-dibromoethane with a selectivity over 95%. The composition of the Pd(OAc)2–LiNO3 solutions was followed during the reaction of ethylene by means of UV–Vis spectroscopy.
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Balandina, T.A., Larina, T.V., Trebushat, D.V. et al. Effect of ionic liquid BMImBr on palladium-catalyzed oxidation of ethylene with LiNO3 . React Kinet Catal Lett 97, 191–197 (2009). https://doi.org/10.1007/s11144-009-0043-z
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DOI: https://doi.org/10.1007/s11144-009-0043-z