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Hydrogenation of calcium carbonate in aqueous systems catalyzed by Rh(I)- and Ru(II)-complexes using poly(methylhydrosiloxane) or hypophosphite as hydrogen sources

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Abstract

The two abundant natural carbon sources, calcium carbonate and carbon dioxide were combined under mild conditions to yield calcium formate and formic acid upon reduction in aqueous systems using poly(methylhydrosiloxane) or sodium hypophosphite as reductants with Rh(I)- and Ru(II)-complexes of monosulfonated triphenylphosphine as catalysts.

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Authors and Affiliations

  1. Institute of Physical Chemistry, University of Debrecen, Debrecen, Hungary

    István Jószai & Ferenc Joó

  2. Research Group of Homogeneous Catalysis Hungarian Academy of Sciences, Debrecen 10, P. O. Box 7, H-4010, Debrecen, Hungary

    Ferenc Joó

Authors
  1. István Jószai
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  2. Ferenc Joó
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Correspondence to Ferenc Joó.

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Jószai, I., Joó, F. Hydrogenation of calcium carbonate in aqueous systems catalyzed by Rh(I)- and Ru(II)-complexes using poly(methylhydrosiloxane) or hypophosphite as hydrogen sources. React Kinet Catal Lett 91, 361–368 (2007). https://doi.org/10.1007/s11144-007-5156-7

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  • DOI: https://doi.org/10.1007/s11144-007-5156-7

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