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Palladium-catalyzed enantioselective allylic substitution by chiral p,n-heterodonor ligands

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Reaction Kinetics and Catalysis Letters Aims and scope Submit manuscript

Summary

Chiral P,N-heterodonor ligands are effective in the enantioselective allylic substitution of 1,2-diphenyl-2-propenyl acetate with dimethylmalonate. The reactions are conveniently carried out at ambient temperature. The excellent levels of enantiomeric excess up to 98% were obtained in good conversion.

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Authors and Affiliations

  1. Department of Chemical Engineering, Inha University,, Incheon 402-751, Korea

    Sang-Han Kim

  2. Department of Chemical Engineering, Inha University,, Incheon 402-751, Korea

    Xiao-Feng Guo

  3. Department of Chemical Engineering, Inha University,, Incheon 402-751, Korea

    Geon-Joong Kim

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  1. Sang-Han Kim
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  2. Xiao-Feng Guo
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  3. Geon-Joong Kim
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Kim, SH., Guo, XF. & Kim, GJ. Palladium-catalyzed enantioselective allylic substitution by chiral p,n-heterodonor ligands. React Kinet Catal Lett 88, 285–291 (2006). https://doi.org/10.1007/s11144-006-0078-3

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  • DOI: https://doi.org/10.1007/s11144-006-0078-3

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