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Absolute rate constants for the reactions of OHradicals withCH 3 CH 2 OH, CF 2 HCH 2 OHandCF 3 CH 2 OH<o:p>

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Summary

Pulsed laser photolysis with resonance fluorescence monitoring of OH radicals was applied at T = 300±2 K to obtain the rate constants of k 1= (3.38±0.60)x10-12, k 2= (2.52±0.44)x10-13and k 3 = (1.06±0.30)x10-13cm3molecule-1s-1with 2σprecision given for the overall reactions OH + CH3CH2OH (1), OH + CF2HCH2OH (2) and OH + CF3CH2OH (3), respectively. k 2is the first direct kinetic data for the reaction of OH radicals with CF2HCH2OH reported in the literature.</o:p>

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Authors and Affiliations

  1. Chemical Research Center, Hungarian Academy of Sciences, Pusztaszeri út 59-67, H-1025 Budapest, Hungary

    Gergely Kovács

  2. Chemical Research Center, Hungarian Academy of Sciences, Pusztaszeri út 59-67, H-1025 Budapest, Hungary

    Tas Szász-Vadász

  3. Department of Chemistry, University of Crete, Heraklion 71409, Crete, Greece

    Vassilis C. Papadimitriou

  4. Chemical Research Center, Hungarian Academy of Sciences, Pusztaszeri út 59-67, H-1025 Budapest, Hungary

    Sándor Dóbé

  5. Chemical Research Center, Hungarian Academy of Sciences, Pusztaszeri út 59-67, H-1025 Budapest, Hungary

    Tibor Bérces

  6. Chemical Research Center, Hungarian Academy of Sciences, Pusztaszeri út 59-67, H-1025 Budapest, Hungary

    Ferenc Márta

Authors
  1. Gergely Kovács
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  2. Tas Szász-Vadász
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  3. Vassilis C. Papadimitriou
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  4. Sándor Dóbé
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  5. Tibor Bérces
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  6. Ferenc Márta
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Kovács, G., Szász-Vadász, T., Papadimitriou, V. et al. Absolute rate constants for the reactions of OHradicals withCH 3 CH 2 OH, CF 2 HCH 2 OHandCF 3 CH 2 OH<o:p> . React Kinet Catal Lett 87, 129–138 (2005). https://doi.org/10.1007/s11144-006-0018-2

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  • DOI: https://doi.org/10.1007/s11144-006-0018-2

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