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Evidence for synchronous cleavage of N-H and C-C bonds: bis(2,2¢-bipyridyl)copper(II) permanganate oxidation of cobalt(III) bound and unbound α-amino acids

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Summary

Oxidation of pentaamminecobalt(III) complexes of α-aminoacids by bis(2,2¢-bipyridyl) copper(II) permanganate in 50% HOAc-50% H2O (v/v) aqueous acetic acid medium. This oxidation as a diagnostic tool to find out the fraction proceeding by synchronous cleavages of N-H and C-C bonds.

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Authors and Affiliations

  1. Department of Chemistry, Annamalai University, Annamalainagar - 608 002, India

    Pownsamy Kannan

  2. Department of Chemistry, Annamalai University, Annamalainagar - 608 002, India

    Kuyam Rathinavelu Sankaran

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  1. Pownsamy Kannan
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  2. Kuyam Rathinavelu Sankaran
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Kannan, P., Sankaran, K. Evidence for synchronous cleavage of N-H and C-C bonds: bis(2,2¢-bipyridyl)copper(II) permanganate oxidation of cobalt(III) bound and unbound α-amino acids. React Kinet Catal Lett 85, 231–238 (2005). https://doi.org/10.1007/s11144-005-0265-7

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  • DOI: https://doi.org/10.1007/s11144-005-0265-7

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