Skip to main content
SpringerLink
Log in

To the theory of electrocapillarity

  • Discussion
  • Published:
Protection of Metals Aims and scope Submit manuscript

Abstract

The possibility of constructing molecular thermodynamics of surface phenomena is demonstrated. It is already 125 years since the main work of J.W. Gibbs “On the Equilibrium of Heterogeneous Substances” [1], where a fundamental theory of capillarity was developed, has been published. Up to now, this theory forms the basis of thermodynamics of almost all the surface phenomena and for exploring novel directions in the surface science.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

REFERENCES

  1. Gibbs, J.W., Termodinamika. Statisticheskaya mekhanika (Thermodynamics. Statistical Mechanics), Moscow: Nauka, 1982.

    Google Scholar 

  2. Grahame, D.C. and Whitney, R.B., J. Amer. Chem. Soc., 1942, vol. 64, p. 1548.

    Google Scholar 

  3. Guggenheim, E.A., Thermodynamics, Amsterdam: North Holland, 1977.

    Google Scholar 

  4. Lenard, A., Wied. Ann., 1892, vol. 46, p. 584.

    Google Scholar 

  5. McTaggari, N., Phil. Mag., 1914, vol. 6, p. 287.

    Google Scholar 

  6. Frumkin, A.N., Collected Works of the Karpov Institute of Physical Chemistry, 1924, issue 2, p. 1060; Frumkin, A.N., Iofa, Z.A., and Gerovich, V.M., Z. Fiz. Khimii, 1956, vol. 30, p. 1455.

  7. Einstein, A., Fizika i real’nost’. Sbornik statei (Physics and Reality. Collected Works), Frankfurt, U.A., Ed., Moscow: Nauka, 1965.

    Google Scholar 

  8. Geguzin, Ya.E., Kaplya (Drop), Moscow: Nauka, 1973.

    Google Scholar 

  9. Jaccard, C., Int. Conf. on Low Temperature. Physics of Snow and Ice, Sapporo, Japan: 1966, p. 14.

    Google Scholar 

  10. Tamm, I.E., Osnovy teorii elektrichestva (Basic Principles of the Theory of Electricity), Moscow: Nauka, 1961.

    Google Scholar 

  11. Parcell, E., Elektrichestvo i magnetizm (Electricity and Magnetism), Moscow: Nauka, 1975.

    Google Scholar 

  12. Rusanov, A.I., Fazovye ravnovesiya i poverkhnostnye yavleniya (Phase Equilibriums and Surface Phenomena), Leningrad: Khimiya, 1967.

    Google Scholar 

  13. Sychev, V.V., Differentsial’nye uravneniya termodinamiki (Differential Equations of Thermodynamics), Moscow: Nauka, 1981, vol. 1.

    Google Scholar 

  14. Sychev, V.V., Differentsial’nye uravneniya termodinamiki (Differential Equations of Thermodynamics), Moscow: Nauka, 1981, vol. 2.

    Google Scholar 

  15. Fröhlich, H., Theory of Dielectrics, Oxford: Clarendon, 1958.

    Google Scholar 

  16. Brown, W.F., Dielectrics, Berlin: Springer, 1956.

    Google Scholar 

  17. Vonsovskii, S.V., Magnetizm (Magnetism), Moscow: Nauka, 1972.

    Google Scholar 

  18. Payne, R., Advances in Electrochemistry and Electrochemical Engineering, 1970, vol. 7, p. 1.

    Google Scholar 

  19. Termodinamicheskie kharakteristiki nevodnykh rastvorov. Spravochnik (Thermodynamic Parameters of Nonaqueous Solutions. Handbook), Poltoratskii, G.M., Ed., Leningrad: Khimiya, 1984.

    Google Scholar 

  20. Bewig, R.E. and Naval, U.S., Research Laboratory Report, Oxford: 1958, p. 5096.

  21. Frumkin, A.N., in Collected Works of the Karpov Institute of Physical Chemistry, Moscow: 1925, issue 4, p. 73.

  22. Frumkin, A.N., Potentsialy nulevogo zaryada (Zero Point Potentials), Moscow: Nauka, 1979.

    Google Scholar 

  23. Trasatti, S., Electrochim. Electrochem. Eng., 1977, vol. 10, p. 213.

    Google Scholar 

  24. Ono, S. and Kondo, S., Molecular Theory of Surface Tension in Liquids, Berlin: Springer, 1960.

    Google Scholar 

  25. Physical Chemistry of Surfaces, Adamson, A. W., Ed., New York: Wiley, 1976.

    Google Scholar 

  26. Kittel, Ch., Thermal Physics, New York: Wiley, 1974.

    Google Scholar 

  27. Dorfman, Ya.G., Diamagnetizm i khimicheskaya svyaz’ (Diamagnetism and Chemical Bond), Moscow: Izd. Fiz.-Mat. Lit., 1961.

    Google Scholar 

  28. Senda, M., Kokiuchi, T., Osaka, T., and Kakutani, T., Itogi Nauki Tekhn. Ser. Elektrokhimiya, Moscow: VINITI, 1988, vol. 28, p. 131.

    Google Scholar 

  29. Kokiuchi, T. and Senda, M., Bull. Chem. Soc, Jpn., 1983, vol. 56, p. 1758.

    Google Scholar 

  30. Salem, R.R., Zh. Fiz. Khim., 1988, vol. 62, no. 6, p. 1582.

    Google Scholar 

  31. Smirnov, N.V. and Stepanov, V.P., Fizicheskaya khimiya. Sovremennye problemy (Physical Chemistry. Modern Problems), Moscow: Khimiya, 1985, pp. 138, 179.

    Google Scholar 

  32. Salem, R.R., Teoriya dvoinogo sloya (Theory of Double Layer), Moscow: Fizmatizdat, 2003.

    Google Scholar 

  33. Frumkin, A.N., Z. Elektrochem., 1923, vol. 103, p. 532.

    Google Scholar 

  34. Damaskin, B.B., Dvoinoi sloi i elektrodnaya kinetika (Double Layer and Electrode Kinetics), Moscow: Nauka, 1981, p. 7.

    Google Scholar 

  35. Damaskin, B.B., Petrii, O.A., and Tsirlina, G.A., Elektrokhimiya (Electrochemistry), Moscow: Khimiya, 2001.

    Google Scholar 

  36. Kir’yanov, V.A., Krylov, V.S., and Grigor’ev, N.B., Elektrokhimiya, 1968, vol. 4, p. 408.

    Google Scholar 

  37. Wolff, G. and von Stackelberg, M., Collect. Czechosl. Chem. Comm., 1965, vol. 30, p. 3989.

    Google Scholar 

  38. Bredig, G., Z. Angew. Chem., 1898, vol. 16, p. 951.

    Google Scholar 

  39. Bredig, G. and Haber, F., Berichte, 1898, vol. 31, p. 2741.

    Google Scholar 

  40. Angerstein, G., Bull. Acad. Polon. Sci., 1955, vol. 3, p. 447.

    Google Scholar 

  41. Kolotyrkin, Ya.M. and Florianovich, G.M., Itogi Nauki Tekhn. Ser. Elektrokhimiya, Moscow: VINITI, 1971, vol. 7, p. 5.

    Google Scholar 

  42. Salzberg, H.W., J. Electrochem. Soc., 1953, vol. 100, p. 589.

    Google Scholar 

  43. Kabanov, B.N., Astakhov, I.I., and Kiseleva, I.G., Usp. Khimii, 1965, vol. 34, p. 181.

    Google Scholar 

  44. Ockrent, C., J. Phys. Chem., 1931, vol. 35, p. 3300.

    Google Scholar 

  45. Salem, R.R., Zh. Fiz. Khim., 1995, vol. 69, no. 2, p. 321.

    Google Scholar 

  46. Bakhshiev, N.G., Vvedenie v molekulyarnuyu spektroskopiyu (Introduction to Molecular Spectroscopy), Leningrad: Izd. Leningr. Univ., 1973.

    Google Scholar 

  47. Nikolaeva, N.V., Frumkin, A.N., and Iofa, Z.A., Zh. Fiz. Khim., 1952, vol. 26, p. 1326.

    Google Scholar 

  48. Vetter, K.J., Elektrochemische Kinetik (Electrochemical Kinetics), Berlin: Springer, 1961.

    Google Scholar 

  49. Frumkin, A.N., Ergebn. Exakt. Naturwiss., 1928, vol. 7, p. 235.

    Google Scholar 

  50. Butler, J.A.V., Proc. Roy. Soc., 1929, vol. 122, p. 399A.

    Google Scholar 

  51. Kirillin, V.A., Sheindlin, A.E., and Shpilrain, E.E., Termodinamika rastvorov (Thermodynamics of Solutions), Moscow: Energiya, 1980.

    Google Scholar 

  52. Delahay, P., Double Layer and Electrode Kinetics, New York: Interscience, 1965.

    Google Scholar 

  53. Trassatti, S., Colloid. Surf., 1980, vol. 1, p. 173.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Higher College of Chemistry, Russian Academy of Sciences, Miusskaya pl. 9, 125047, Moscow, Russia

    R. R. Salem

Authors
  1. R. R. Salem
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Zashchita Metallov, Vol. 41, No. 1, 2005, pp. 91–106.

Original Russian Text Copyright © 2005 by Salem.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Salem, R.R. To the theory of electrocapillarity. Prot Met 41, 84–98 (2005). https://doi.org/10.1007/s11124-005-0012-5

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11124-005-0012-5

Keywords

Search

Navigation