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Nanostructured manganese oxide on silica aerogel: a new catalyst toward water oxidation

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Abstract

Herein we report on the synthesis and characterization of nano-sized Mn oxide/silica aerogel with low density as a good catalyst toward water oxidation. The composite was synthesized by a simple and low-cost hydrothermal procedure. In the next step, we studied the composite in the presence of cerium(IV) ammonium nitrate and photo-produced Ru(bpy) 3+3 as a water-oxidizing catalyst. The low-density composite is a good Mn-based catalyst with turnover frequencies of ~0.3 and 0.5 (mmol O2/(mol Mn·s)) in the presence of Ru(bpy) 3+3 and cerium(IV) ammonium nitrate, respectively. In addition to the water-oxidizing activities of the composite under different conditions, its self-healing reaction in the presence of cerium(IV) ammonium nitrate was also studied.

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Acknowledgments

MMN, SS, and SM are grateful to the Institute for Advanced Studies in Basic Sciences. This work was supported by Grant-in-Aids for Scientific Research from the Ministry of Education of Japan (24370025 and 26220801) to TT. SIA was supported by grant from the Russian Science Foundation (No: 14-14-00039).

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Authors and Affiliations

  1. Department of Chemistry, Institute for Advanced Studies in Basic Sciences (IASBS), Zanjan, 45137-66731, Iran

    Mohammad Mahdi Najafpour, Saeideh Salimi & Sepideh Madadkhani

  2. Center of Climate Change and Global Warming, Institute for Advanced Studies in Basic Sciences (IASBS), Zanjan, 45137-66731, Iran

    Mohammad Mahdi Najafpour

  3. Fachbereich Chemie and Wissenschaftliches Zentrum für Materialwissenschaften (WZMW), Philipps-Universität Marburg, Hans-Meerwein-Straße, 35032, Marburg, Germany

    Małgorzata Hołyńska

  4. Department of Biology, Faculty of Science, Tokyo University of Science, Kagurazaka 1-3, Shinjuku-ku, Tokyo, 162-8601, Japan

    Tatsuya Tomo

  5. PRESTO, Japan Science and Technology Agency (JST), 4-1-8 Honcho Kawaguchi, Saitama, 332-0012, Japan

    Tatsuya Tomo

  6. Controlled Photobiosynthesis Laboratory, Institute of Plant Physiology, Russian Academy of Sciences, Botanicheskaya Street 35, Moscow, Russia, 127276

    Suleyman I. Allakhverdiev

  7. Institute of Basic Biological Problems, Russian Academy of Sciences, Pushchino, Moscow Region, Russia, 142290

    Suleyman I. Allakhverdiev

  8. Department of Plant Physiology, Faculty of Biology, M.V. Lomonosov Moscow State University, Leninskie Gory 1-12, Moscow, Russia, 119991

    Suleyman I. Allakhverdiev

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  1. Mohammad Mahdi Najafpour
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  2. Saeideh Salimi
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  3. Sepideh Madadkhani
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  4. Małgorzata Hołyńska
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  5. Tatsuya Tomo
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  6. Suleyman I. Allakhverdiev
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Corresponding authors

Correspondence to Mohammad Mahdi Najafpour or Suleyman I. Allakhverdiev.

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Najafpour, M.M., Salimi, S., Madadkhani, S. et al. Nanostructured manganese oxide on silica aerogel: a new catalyst toward water oxidation. Photosynth Res 130, 225–235 (2016). https://doi.org/10.1007/s11120-016-0247-9

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