The wetting of solid titanium substrates with liquid lithium and magnesium fluorides was studied by the sessile drop method in 1 · 10–3 Pa vacuum at 1173 and 1553 K, respectively. Titanium and fluorine were found to actively interact in the systems to change the titanium substrate surface profile, leading to a ‘crater’ in the contact area. The ‘solid titanium–liquid magnesium fluoride’ interfacial geometry was examined and confirmed the potential to form gaseous products in the titanium–fluorine interaction. Such gaseous compounds prevent the wetting of alkaline-earth metal fluorides with titanium-containing melts at temperatures above 1400 K. This allows the materials made of alkaline-earth metal fluorides to be used as refractories for high-temperature melting, longterm homogenization, and casting of alloys with a high content of Ti, Zr, Hf, Nb, and V.
Similar content being viewed by others
References
Akihisa Inoue, “High strength bulk amorphous alloys with low critical cooling rates (overview),” Mater. Trans. JIM, 36, No. 7, 866–875 (1995).
E. Matsubara and Y. Waseda, “Structural studies of new metallic amorphous alloys with wide supercooled liquid region (overview),” Mater. Trans. JIM, 36, No. 7, 883–889 (1995).
K. Ootsuka, K. Shimizu, and Yu. Suzuki, Shape Memory Alloys [Russian translation], Metallurgiya, Moscow (1990), p. 227.
T.W. Duerig, K.N. Melton, D. Stockel, and C.M. Wayman, Engineering Aspects of Shape Memory Alloys, Butterworth-Heinemann Ltd (1990), p. 449.
Yu.V. Naidich, “The wettability of solids by liquid metals,” Prog. Surf. Membr. Sci., 14, 353–484 (1981).
Y.V. Naidich and V.P. Krasovsky, “The nonwettability behavior of solid substrates in contact with chemical active rich Ti-, Zr-, Hf-liquid alloys,” J. Mater. Sci. Lett., 17, 683–685 (1998).
V.P. Krasovskii and Y.V. Naidich, “Wettability of calcium fluoride by V-, Nb-, and Cr-containing liquid alloys,” Powder Metall. Met. Ceram., 41, No. 1–2, 72–75 (2002).
N. Froumin, S. Barzilai, M. Aizenshtein, M. Lomberg, and N. Frage, “Wetting induced by near-surface Tienrichment in the CaF2/In–Ti and CaF2/Cu–Ti systems,” J. Mater. Sci. Eng., 495A, 181–186 (2008).
S. Barzilai, N. Argaman, N. Froumin, D. Fuks, and N. Frage, “The effect of Ti on the wetting CaF2 substrate by In–Ti and Ga–Ti alloys. Ab-initio consideration,”Appl. Phys. A, 93, 379–385 (2008).
S. Barzilai, N. Argaman, N. Froumin, D. Fuks, and N. Frage, “The effect of Me–Ti inter-atomic interactions on wetting in CaF2/(Me–Ti) systems: Ab-initio considerations,” Surf. Sci., 603, 2096–2101 (2009).
E. Glickman, D. Fuks, N. Frage, S. Barzilai, and N. Froumin, “Adsorption effect in non-reaction wetting: In–Ti on CaF2,” Appl. Phys. A, 106, No. 1, 181–189 (2012).
V. Krasovskyy, "Contact interaction and wetting of strontium fluoride by metal melts," J. Adhes. Sci. Technol., 26, No. 3, 1221–1231 (2012).
Yu.V. Naidich and V.P. Krasovskyy, “Interaction of metallic melts with refractory fluorides and development of new refractories for melting of active metals,” in: Current Issues of Modern Materials Science [in Russian], Akademperiodika, Kyiv (2008), pp. 431–452.
Yu.V. Naidich, V.P. Krasovskyy, and Yu.N. Chuvashov, “Wetting of magnesium, barium, and calcium fluorides with metallic melts,” Adgez. Raspl. Paika Mater., No. 24, 33–36 (1990).
V. Krasovsky and Y. Naidich, “Capillary properties of alloys containing chemically active metals in contact with fluoride refractories,” Trans. JWRI. Special Issue, 30, 61–68 (2001).
G.B. Bokii, Crystal Chemistry [in Russian], Nauka, Moscow (1971), p. 236.
A.I. Efimov, L.P. Belorukova, I.V. Vasilkova, and V.P. Chechev, Properties of Inorganic Compounds: Handbook [in Russian], Khimiya, Leningrad (1983), p. 392.
W.A. Weyl, “The total ceramic spectrum,” Ceram. Age, 60, No. 5, 28–31 (1952).
V.P. Krasovskyy, B.V. Fenochka, and Yu.N. Chuvashov, “Contact interaction of titanium-containing alloys and rare earth metal difluorides,” Adgez. Raspl. Paika Mater., No. 28, 26–30 (1992).
Author information
Authors and Affiliations
Corresponding author
Additional information
Translated from Poroshkova Metallurgiya, Vol. 58, Nos. 5–6 (527), pp. 111–119, 2019.
Rights and permissions
About this article
Cite this article
Krasovskyy, V. Interaction of Single-Crystalline Metal Fluorides with Titanium-Containing Melts. Powder Metall Met Ceram 58, 334–340 (2019). https://doi.org/10.1007/s11106-019-00083-y
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11106-019-00083-y