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Phase Equilibria in the Aluminum Corner of the Al–Ti–Pt System

  • PHYSICOCHEMICAL MATERIALS RESEARCH
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Powder Metallurgy and Metal Ceramics Aims and scope

A series of physicochemical analysis techniques are employed to study the phase equilibria in the aluminum corner of the Al–Ti–Pt system at subsolidus temperatures and in the alloy crystallization process. It has been established for the first time that a ternary τ1 phase (AuCu3 structural type) forms by peritectic reaction L + <Ti2Al5> + <TiAl> ⇄ τ1 at 1405°C. On the solidus surface in the studied composition range at 1405, 1310, 1275, 1060, 925, 820, and 660°C, there are seven isothermal planes that participate in invariant four-phase equilibria involving the liquid phase, three of them being peritectic and the others transitional.

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References

  1. J. J. Ding, P. Rogl, B. Chevalier, and J. Etourneau, “Structural chemistry and phase relations in the systems Ti–{Pd, Pt}–Al,” Intermetallics, 8, No. 12, 1377–1384 (2000).

    Article  Google Scholar 

  2. X. Yan, A. Grytsiv, P. Rogl, et al., “Laves phases in the ternary systems Ti–{Pd, Pt}–Al,” Intermetallics, 17, No. 5, 336–342 (2009).

    Article  Google Scholar 

  3. A. Grytsiv, P. Rogl, H. Schmidt, et al., “Formation and crystal chemistry of cubic ternary phases with filled Th6Mn23-type and AuCu3-type in the systems Ti–MVIII–Al,” Intermetallics, 12, No. 5, 563–577 (2004).

    Article  Google Scholar 

  4. O. V. Zaikina, V. G. Khorujaya, D. Pavlyuchkov, et al., “Investigation of the Al–Ti–Pt alloy system at 1100°C,” J. Alloys Compd., 509, No. 28, 7565–7571 (2011).

    Article  Google Scholar 

  5. O. Zaikina, D. Pavlyuchkov, V. Khorujaya, and T. Velikanova, “X-ray powder diffraction data for new ternary phases in the Al–Ti–Pt system,” Powder Diffr., 23, No. 4, 360–362 (2008).

    Article  Google Scholar 

  6. S. Samuha, D. Pavlyuchkov, O. V. Zaikina, et al., “Crystal structures of the Al–Ti–Pt τ5 and τ6 phases solved by zonal precession electron diffraction,” J. Alloys Compd., 621, 47–52 (2015).

    Article  Google Scholar 

  7. V. T. Witusiewicz, A. A. Bondar, U. Hecht, et al., “The Al–B–Nb–Ti system. III. Thermodynamic reevaluation of the constituent binary system Al–Ti,” J. Alloys Compd., 465, Nos. 1–2, 64–77 (2008).

    Article  Google Scholar 

  8. A. J. McAlister and D. J. Kahan, “The Al–Pt (aluminum–platinum) system,” Bull. Alloy Phase Diagrams, 7, No. 1, 47–51 (1986).

    Article  Google Scholar 

  9. B. Grushko, D. Kapush, J. Su, et al., “Al-rich region of Al–Pt,” J. Alloys Compd., 580, No. 15, 618–625 (2013).

    Article  Google Scholar 

  10. P. Villars and L. D. Calvert, Pearson’s Handbook of Crystallographic Data for Intermetallic Phases, in 3 vols., ASM, Metals Park, Ohio (1985), p. 5366.

  11. S. Stilz and A. Prince, “Al–Be–Ti,” in: G. Petzow and G. Effenberg (eds.), Ternary Alloys, VCH (1990), Vol. 3, p. 374.

  12. J. Braun, M. Ellner, and B. Predel, “Experimental studies on the structure and stability of the TiAl phase,” Z. Metallkd., 86, No. 12, 870–876 (1995).

    Google Scholar 

  13. J. Braun and M. Ellner, “Phase equilibria investigations on the aluminum-rich part of the binary system Ti–Al,” Met. Mater. Trans., 32A, No. 5, 1037–1048 (2001).

    Article  Google Scholar 

  14. J. C. Schuster and H. Ipser, “Phases and phase equilibria in the partial system TiAl3–TiAl,” Z. Metallkd., 81, No. 6, 383–386 (1990).

    Google Scholar 

  15. M. Woerle, F. Krumeich, T. Chatterji, et al., “On the structure and twinning of PtAl4,” J. Alloys Compd., 455, Nos. 1–2, 130–136 (2008).

    Article  Google Scholar 

  16. M. Ellner, U. Kattner, and B. Predel, “Studies on the constitution and structure in the aluminum-rich part of the Ni–Al and Pt–Al systems,” J. Less-Common Met., 87, No. 2, 305–325 (1982).

    Article  Google Scholar 

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Correspondence to K. E. Kornienko.

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Translated from Poroshkova Metallurgiya, Vol. 57, Nos. 1–2 (519), pp. 144–158, 2018.

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Zaikina, O.V., Khoruzha, V.G., Kornienko, K.E. et al. Phase Equilibria in the Aluminum Corner of the Al–Ti–Pt System. Powder Metall Met Ceram 57, 114–126 (2018). https://doi.org/10.1007/s11106-018-9959-z

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  • DOI: https://doi.org/10.1007/s11106-018-9959-z

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