Skip to main content
Log in

Wear- and Corrosion-Resistant Cr3C2–15 % Ni and Cr3C2–28 % Ni Hard Alloys: Production and Industrial Testing of Valves for Oil Well Pumps from these Materials

  • POWDER METALLURGY INDUSTRY AND MANAGERIAL ECONOMICS
  • Published:
Powder Metallurgy and Metal Ceramics Aims and scope

The corrosion resistance of Cr 3 C 2 –15 % Ni (KKhNF15) alloy in solutions of acids, alkalis, and salts is studied. It is found that the corrosion rate of this alloy is one fifth to one thirtieth that of 40Cr13 (40Kh13) stainless steel, stellite, and WC–8 % Co (VK8) alloy used to manufacture valve pairs for oil well pumps. The production of balls from the sintered Cr 3 C 2 –15 % Ni (KKhNF15) alloy and of valve seats from the Cr 3 C 2 –28 % Ni (KKhNF28) alloy is examined. The modes of rough machining, finishing, and abrasive mechanical processing of chromium carbide hard alloys are optimized depending on the duration of processes and the particle size of B 4 C powder. The batches of valve pairs manufactured from chromium carbide alloys were tested in industrial conditions at enterprises of the Ukrnafta Oil and Gas Company. The service life of a valve assembly made of the corrosion-resistant hard alloys is more than two years, which is three to five times higher than the life of such parts made of conventional materials. The standards developed for ‘seat–ball’ valve pairs from chromium carbide alloys are indicated (TU U. 28.4–02126745–001–2002).

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4

Similar content being viewed by others

References

  1. R. Kieffer and F. Benezovsky, Hardmetals [German translation], Springer-Verlag, Vienna (1963).

    Google Scholar 

  2. V. I. Tret’yakov, Fundamentals of Physical Metallurgy and Production Technology for Sintered Hardmetals [in Russian], 2nd ed., Metallurgiya, Moscow (1976), p. 528.

    Google Scholar 

  3. Yu. A. Geller and A. G. Rakhshtadt, Materials Science [in Russian], Metallurgiya, Moscow (1975), p. 447.

    Google Scholar 

  4. V. V. Grigorieva and V. M. Klimenko, Chromium Carbide Alloys [in Ukrainian], Vyd. AN URSR, Kiev (1961), p. 55.

    Google Scholar 

  5. V. N. Klimenko and V. A. Maslyuk, “Corrosion-resistant metal ceramic chromium carbide alloys,” Tekhnol. Org. Proizv., No. 3, 53–58 (1970).

    Google Scholar 

  6. V. N. Klimenko and V. A. Maslyuk, “Chromium carbide–nickel–phosphorus alloys, their properties, and application,” Pokrok. Prask. Metal., No. 1–2, 70–79 (1977).

    Google Scholar 

  7. V. A. Maslyuk, Scientific and Technological Principles for Producing Powder Composites from Hard Chromium Compounds for Wear- and Corrosion-Resistant Parts and Coatings [in Ukrainian], Author’s Abstract of ScD Thesis: 05.16.06, Kiev (1994), p. 46.

  8. V. A. Maslyuk, “Effect of method of preparation of a nickel–phosphorus master alloy on the structure and properties of a chromium carbide alloy cemented with 15 % of a binder based on this alloy,” Powder Metall. Met. Ceram., 22, No. 12, 1003–1006 (1983).

    Article  Google Scholar 

  9. V. Ya. Naumenko, Yu. V. Momot, and V. I. Ivchenko, “Development of corrosion-resistant materials for producing valve “seat–ball” for oil well pumps,” Nauk. Visn. Ivano-Frank. Nats. Univ. Naft. Gazy, 27, No. 1, 51–60 (2011).

  10. V. Ya. Naumenko, E. I. Palytsya, M. V. Ligotskii, et al., “Application of new metal ceramic composites in oil and gas production,” Naft. Gas. Promyslov., No. 6, 34–35 (2000).

  11. V. A. Maslyuk, V. N. Neschetnyi, V. S. Lugovskaya, and Yu. V. Sambros, “Corrosion resistance of chromium carbide-base cemented carbides in a marine atmosphere,” Powder Metall. Met. Ceram., 31, No. 7, 586–588 (1992).

    Google Scholar 

  12. V. Ya. Naumenko, Device for Rough Machining of Balls [in Ukrainian], Ukrainian Patent No. 51312, IPC B 24 B 11/00; appl. January 26, 2010; publ. July 12 (2010), Bulletin No. 13, p. 6.

  13. V. Ya. Naumenko, Device for Finishing of Balls [in Ukrainian], Ukrainian Patent No. 51313, IPC B 24 11/00; appl. January 26, 2010; publ. July 12 (2010), Bulletin No. 13, p. 5.

  14. T. Ya. Kosolapova and G. V. Samsonov, “Resistance of chromium carbides in acids and alkaline solutions,” Ukr. Khim. Zh., 28, 931–939 (1962).

  15. J. Hinüber and O. Rüdiger, “Arch,” Eisenhüttenwes, 24, 267–265 (1953).

    Google Scholar 

  16. T. Ya. Kosolapova, Carbides [in Russian], Metallurgiya, Moscow (1968), p. 300.

    Google Scholar 

  17. H. H. Uhlig and R. W. Revie, Corrosion and Corrosion Control, Wiley-Interscience, New York (1985).

    Google Scholar 

  18. TU U.28.4–02126745–001–2002, Metal Ceramic Valve Pairs “Seat–Ball” [in Ukrainian], Derzhstandart Ukrainy, Kiev (2000), p. 16.

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to V. A. Maslyuk.

Additional information

Translated from Poroshkovaya Metallurgiya, Vol. 54, Nos. 3–4 (502), pp. 126–135, 2015.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Maslyuk, V.A., Naumenko, V.Y., Ivchenko, V.I. et al. Wear- and Corrosion-Resistant Cr3C2–15 % Ni and Cr3C2–28 % Ni Hard Alloys: Production and Industrial Testing of Valves for Oil Well Pumps from these Materials. Powder Metall Met Ceram 54, 227–233 (2015). https://doi.org/10.1007/s11106-015-9704-9

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11106-015-9704-9

Keywords

Navigation