A methodological approach to the design of ceramics with predetermined composition and microstructure is proposed. Its fundamental idea is to implement the accumulated knowledge into existing technologies or develop novel science-based technologies. The choice of a known microstructure and the design of a novel one is based on the knowledge accumulated so far on material structurization and properties as follows: knowledge systematization – analysis – generalization – establishment of regularities. The ideology of designing a novel material with predetermined microstructure consists in implementing the following sequence of stages: knowledge-based choice of microstructure and sintering conditions → manufacture of a pilot sample of the material (prototype) → study of the properties → optimization of the microstructure and properties → technology. An algorithm is proposed for designing a material with required microstructure, which can be achieved through coordinated structural transformations during sintering, whose evolution determines the formation of planned microstructural elements, their crystalline morphology, size, content, and distribution throughout the volume. An example is provided for designing the microstructure of silicon carbide material with a SiC–B4C eutectic binder.
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References
I. N. Frantsevich and A. N. Pilyankevich, “On interrelation of geometric and energy structure of solids,” in: Effect of High Pressures on Substance [in Russian], Vol. 1, Kiev (1987), pp. 86–91.
V. V. Skorokhod, “Principles of microstructural engineering in powder metallurgy,” in: Proc. 17th All-Union Conf. Powder Metallurgy (October 21–25, 1991), Inst. Probl. Materialoved. USSR, Kiev (1991).
Yu. D. Tret’yakov, “Principles of creating new solid-phase materials,” Izv. AN SSSR. Neorg. Mater., No. 5, 693–701 (1985).
Yu. D. Tret’yakov, “Development of inorganic chemistry as a fundamental basis for developing new generations of functional materials,” Usp. Khim., 73, No. 9, 899–916 (2004).
N. N. Kiseleva, V. A. Dudarev, and V. S. Zemskov, “Computer information resources of inorganic chemistry and materials science,” Usp. Khim., 79, No. 2, 162–188 (2010).
A. M. Glezer, “Principles of creating multifunctional structural materials of new generation,” Usp. Fiz. Nauk, 182, No. 5, 559–566 (2011).
V. V. Skorokhod, “Hierarchic concept of structural levels and structural engineering of inorganic materials,” Powder Metall. Met. Ceram., 48, No. 7–8, 396–405 (2009).
R. J. Brook, “Fabrication principles for the production of ceramics with superior mechanical properties,” Proc. Brit. Ceram. Soc., No. 32, 7–24 (1982).
Marin P. Harmer, Helen M. Chan, and Gary F. Miller, “Unique opportunities for microstructural engineering with duplex and laminar composites,” J. Am. Ceram. Soc., 75, No. 7, 1715–1728 (1992).
P. F. Becher, “Microstructural design of toughened ceramics,” J. Am. Ceram. Soc., 74, No. 2, 255–269 (1991).
T. Watanabe, “Toughening of brittle materials by grain boundary design and control,” Mater. Sci. Forum, 126–128, 295–304 (1993).
W. M. Kriven, “Martensitic toughening of ceramics,” Mater. Sci. Eng. A, 127, 249–255 (1990).
A. N. Pilyankevich, G. S. Oleinik, and V. F. Britun, “Structural mechanisms of dispersion of the grain structure in ceramic materials,” Powder Metall. Met. Ceram., 29, No. 1, 30–37 (1990).
G. S. Oleinik, “Formation of fine-grained states in ceramic materials,” in: Fracture Mechanics and Physics of Brittle Materials [in Russian], Inst. Probl. Materialoved. NAN Ukrainy, Kiev (1992), pp. 4–33.
G. S. Oleinik, N. V. Danilenko, and N. P. Bezhenar’, “Processes of forming intragranular boundaries in ceramic materials,” in: Nanostructured Materials (Collected Scientific Papers) [in Russian], Inst. Probl. Materialoved. NAN Ukrainy, Kiev (1998), pp. 93–125.
G. S. Oleinik, Structurization of Materials Based on Covalent Substances [in Russian], ScD Thesis, Inst. Probl. Materialoved. AN USSR, Kiev (1987), p. 311.
G. S. Oleinik and N. V. Danilenko, Plastic Deformation in Ceramics [in Russian], Preprint No. 10, Inst. Probl. Materialoved. NAN Ukrainy, Kiev (1997).
G. S. Oleinik and N. V. Danilenko, “Evolution of deformation substructure in diamond crystals and diamond-like phases (BN, SiC, AlN) in thermal treatment under pressure,” in: Electron Microscopy and Strength of Materials [in Russian], Inst. Probl. Materialoved. NAN Ukrainy, Kiev (1999), pp. 106–128.
G. S. Oleinik, N. V. Danilenko, and Yu. I. Lezhnenko, “Primary crystallization of ceramic materials,” in: Electron Microscopy and Strength of Materials [in Russian], Inst. Probl. Materialoved. NAN Ukrainy, Kiev (1995), pp. 4–38.
G. S. Oleinik, “Structural transformations in the creation of single-phase superhard materials based on dense carbon and boron nitride phases at high pressures and temperatures,” Sverkhtverd. Mater., No. 4, 3–30 (2011).
G. S. Oleinik, “Structural transformations in the creation of superhard materials based on starting powders of wurtzite boron nitride, Sverkhtverd. Mater., No. 1, 3–26 (2012).
V. M. Volkogon and G. S. Oleinik, “Effect of preliminary treatment by rolling of BNw powders on the wurtzite–sphalerite transformation during sintering of hexanit-R,” Sverkhtverd. Mater., No. 1, 22–31 (2003).
G. S. Oleinik and N. V. Danilenko, “Abnormal growth of grains in ceramics.” in: Electron Microscopy and Strength of Materials [in Russian], Inst. Probl. Materialoved. NAN Ukrainy, Kiev (1996), pp. 89–119.
G. S. Oleinik, N. V. Danilenko, and O. N. Kaidash, “Microstructural types of in situ-reinforced ceramics,” Ceramics, Polish Ceram. Bull. 12, Vol. 50, Polish Academy of Science, Krakow (1996), pp. 117–134.
M. P. Shaskol’skaya, Crystallography [in Russian], Vysshaya Shkola, Moscow (1976), p. 390.
O. A. Kaibyshev and R. Z. Valiev, Grain Boundaries and Properties of Metals [in Russian], Metallurgiya, Moscow (1987), p. 212.
V. Yu. Novikov, Secondary Recrystallization [in Russian], Metallurgiya, Moscow (1990), p. 128.
M. H. Lewis, G. Leng-Ward, and S. Mason, “Microstructural design of high temperature ceramics,” Brit. Ceram. Proc., 1–13 (1987).
“Microstructure of high temperature engineering ceramics,” in: Proc. Inst. Phys. Conf. New Mater. and Their Appl. (September 22–25, 1987), Bristol, Philadelphia (1988), pp. 41–51.
J. Dusza, “Possibilities of reliability improvement in advanced structural ceramics,” Pokr. Prask. Met. VUPM, No. 1, 23–71 (1993).
K. Berroth, “Hightemperaturtechnik—Keramische Werkstoffe, Integrationskonzepte, Anwendungen,” Keram. Zeit, 46, No. 1, 13–24 (1994).
“Trends in the development of materials for superhigh temperatures,” Curr. Adv. Mater. Proc., 4, No. 5, 1670–1671 (1991).
E. Beier, “Keramickwerkstoffe fur Flugzeuge und Raumfahrzeuge,” Technica (Suisse), 41, No. 26, 27–30 (1992).
J. Raj, “Fundamental research in structural ceramics for service near 2000°C,” J. Am. Ceram. Soc., 76, No. 9, 2147–2174 (1993).
A. N. Tolstun, V. M. Kiiko, V. N. Kurlov, et al., “Production, microstructure, and mechanical properties of some eutectic oxide fibers,” Deform. Razrush. Mater., No. 3, 12–20 (2007).
S. T. Mileiko, “High-temperature ceramic-matrix composites,” Deform. Razrush. Mater., No. 5, 21–29 (2011).
T. Noda, H. Araki, F. Abe, and M. Okada, “Microstructure and mechanical properties of CVI carbon fiber/SiC composites,” J. Nucl. Mater., 191–194, 539–543 (1992).
Y. Harada, T. Suzuki, K. Hirano, et al., “Creep behaviors of in situ single-crystal Al2O3/YAG and Al2O3/GaP eutectic composites,” J. Ceram. Soc. Japan, 112, No. 5, 294–298 (2004).
G. H. Campbell, B. J. Delgleish, and A. G. Evans, “Brittle-to-ductile transition in silicon carbide,” J. Am. Ceram. Soc., 72, No. 8, 1402–1408 (1989).
A. N. Pilyankevich, A. V. Kurdyumov, G. S. Oleinik, and N. F. Ostrovskaya, “Structure of graphite crystallized in SiC–B eutectic alloys,” Izv. AN SSSR, Neorg. Mater., 14, No. 1, 82–84 (1978).
E. Laurent-Pinson, G. Nouet, and J. Vicens, “Grain boundary studies in 4H and 6H silicon carbide in as-sintered state after high temperature deformation,” in: Proc. 9th Eur. Congr. Electron Microsc. EUREM 88 (September 4–9, 1988), Vol. 2, Bristol, Philadelphia (1988), pp. 543–544.
Mark E. Sixta, Xiao Feng Zhang, and Lutgard C. De Jonghe, “Flexural creep of an in situ-toughened silicon carbide,” J. Am. Ceram. Soc., 84, No. 9, 2022–2028 (2001).
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Translated from Poroshkovaya Metallurgiya, Vol. 51, No. 11–12 (488), pp. 117–138, 2012.
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Oleinik, G.S. Microstructural Design of Ceramics. Powder Metall Met Ceram 51, 709–723 (2013). https://doi.org/10.1007/s11106-013-9486-x
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DOI: https://doi.org/10.1007/s11106-013-9486-x