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Catalytic systems based on multicomponent oxides of 3d-metals and Si-containing carriers for CO oxidation reaction

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Powder Metallurgy and Metal Ceramics Aims and scope

The catalytic activity and surface properties of Cu–Co–Fe oxide catalysts formed on silica gel, powdery β-SiC, and β-SiC nanofibers for CO oxidation reaction are studied. A method, involving including initial acidic treatment of silicon carbide nanofibers with a mixture of hydrofluoric and nitric acids, has been developed for obtaining a highly defective surface layer for the formation of Cu2(OH)3NO3 active mass.

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References

  1. G. I. Golodets, Heterogeneous Catalytic Reaction Involving Molecular Oxygen, Elsevier Science Publishing Company, Amsterdam (1983), p. 567.

    Google Scholar 

  2. V. P. Zhdanov, “Simulation of the effect of surface oxide formation on bistability in CO oxidation on Ptgroup metals,” J. Chem. Phys., 126, 135–142 (2007).

    Google Scholar 

  3. V. V. Goncharuk, G. L. Kamalov, G. O. Kovtun, etc. Catalysis. Mechanisms of Homogeneous and Heterogeneous Catalysis, Cluster Approaches [in Russian], Naukova Dumka, Kiev (2002).

    Google Scholar 

  4. O. A. Krylov, Catalytic Properties of Transition Metals and Their Oxides [in Russian], Nauka, Moscow (1983), p. 312.

    Google Scholar 

  5. V. K. Yatsimirskii, E. V. Ishchenko, Yu. V. Maksimov, et al., “Physicochemical properties and catalytic activity of oxide Fe–Co–Cu catalysts in CO oxidation reaction,” Teor. Éksp. Khim., 39, No. 6, 70–72 (2003).

    Google Scholar 

  6. V. K. Yatskimirskii, O. V. Ishchenko, and S. V. Gaidai, “Peculiarities of oxide Fe–Co–Cu catalysts for CO oxidation reaction,” in: Physics and Chemistry of Condensed Systems and Interfaces [in Ukrainian], Kyiv University Publishing Center, Kiev (2003), p. 27.

    Google Scholar 

  7. E. V. Ishchenko, V. K. Yatsimirskii, A. G. Dyachenko, et al., “Oxide Cu–Co–Fe catalysts of CO oxidation coated on carbon nanotubes,” Teor. Éksp. Khim., 42, No. 4, 222–226 (2006).

    Google Scholar 

  8. O. V. Ishchenko, V. K. Yatsimirskii, S. V. Gaidai, et al., Low-Temperature Catalysts for CO Oxidation Reaction, Including Oxide Cu–Co–Fe System and Carbon Nanotubes [in Ukrainian], Declarative Patent for Useful Model No. 14794, appl. January 10, 2006; publ. in Bulletin No. 5, May 15 (2006).

  9. O. V. Ishchenko, A. G. Dyachenko, A. V. Yatsimirskii, et al., “SiO2 as a carrier of oxide Cu–Co–Fe catalysts of CO oxidation reaction,” Ukr. Khim. Zh., 74, No. 4, 85–87 (2008).

    CAS  Google Scholar 

  10. P. M. Silenko, A. N. Shlapak, T. V. Tomila, et al., “Synthesis of SiC nanofibers from methylchlorosilane using Fe catalyst,” Neorg. Mater., 44, No. 4, 455–461 (2008).

    Article  Google Scholar 

  11. V. V. Pokropivnyi and P. M. Silenko, “Nanotubes and nanotube fibers of silicon carbide: synthesis, stability, structure, and classification,” Teor. Éksp. Khim., 42, No. 1, 3–13 (2006).

    CAS  Google Scholar 

  12. P. M. Silenko, A. N. Shlapak, and I. Yu. Okun’, “Production of nanofiber structures of silicon carbide by thermal decomposition of methylchlorosilane,” in: Proc. Int. Conf. Modern Materials Science: Advances and Challenges (September 26–30, 2005) [in Russian], Kiev (2005), pp. 742–743.

  13. P. M. Silenko, A. M. Shlapak, and Yu. M. Solonin, “Nano- and microfibers of titanium carbide,” in: Proc. 2nd Int. Sci. Conf. Nanostructured Materials-2010: Belarus, Russia, Ukraine (October 19–22, 2010) [in Russian], Kiev (2010).

  14. P. M. Silenko, A. N. Shlapak, O. F. Pilipchuk, et al., “Synthesis of SiC submicron and nanofibers in channels and pores of cordierite honeycomb material,” in: Proc. 2nd Samsonov Conference Materials Science of Refractory Compounds (May 18–20, 2010) [in Russian], Kiev (2010), p. 168.

  15. P. M. Silenko, A. M. Shlapak, and A. V. Ragulya, A Method for Producing Silicon Carbide Nanofibers [in Ukrainian], Ukrainian Patent No. 81534, appl. March 22, 06; publ. January 10 (2008).

  16. P. M. Silenko, A. M. Shlapak, S. M. Kaverina, et al., A Method for Producing Silicon Carbide Nanofibers [in Ukrainian], Ukrainian Patent No. 79767, appl. July 30, 2004; publ. July 25 (2007).

  17. V. K. Yatsimirskii, E. V. Ishchenko, and S. V. Gaidai, “Temperature hysteresis in CO oxidation reaction on complex oxide catalysts,” Teor. Éksp. Khim., 41, No. 5, 323–327 (2005).

    Google Scholar 

  18. O. V. Ishchenko, Mass Spectrometry: Tutorial for Masters of Chemical Department [in Ukrainian], Kyiv University Publishing Center, Kiev (1998), p. 45.

    Google Scholar 

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Correspondence to O. V. Ishchenko.

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Translated from Poroshkovaya Metallurgiya, Vol. 50, No. 9–10 (481), pp. 110–121, 2011.

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Ishchenko, O.V., Silenko, P.M., Zakharova, T.M. et al. Catalytic systems based on multicomponent oxides of 3d-metals and Si-containing carriers for CO oxidation reaction. Powder Metall Met Ceram 50, 662–670 (2012). https://doi.org/10.1007/s11106-012-9372-y

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  • DOI: https://doi.org/10.1007/s11106-012-9372-y

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