Good-quality bilayer coatings with a carbon interlayer and outer carbonate hydroxyapatite layer are obtained on AISI 316L stainless steel substrate using RF PACVD and sol-gel methods. It is found that protective properties of both composite C/HAP coating and HAP coating depend on the temperature of heat treatment. Hydroxyapatite with a carbon interlayer coating annealed at 500°C significantly improves corrosion resistance of the stainless-steel substrate as well as of unary carbon and HAP coatings. The composite C/HAP coating annealed at 500°C exhibits better corrosion resistance in comparison with the HAP coating heated at the same temperature. Stainless-steel substrates with a HAP and C interlayer heated at 700°C have worse corrosion features in comparison with uncoated AISI 316L. The weak corrosion resistance of this sample is due to the formation of metal carbides at this temperature.
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References
W. Cao and L. L. Hench, “Bioactive materials,” Ceram. Int., 22, 493–507 (1996).
L. L. Hench, “Bioceramics: from concept to clinic,” J. Am. Ceram. Soc., 74, 485–510 (1991).
Y. C. Tsui, C. Doyle, and T. W. Clyne, “Plasma sprayed hydroxyapatite coatings on titanium substrates,” Biomaterials, 19, part 1 and 2, 2015–204 (1998).
C. F. Koch, S. Johnson, D. Kumar, et al., “Pulsed laser deposition of hydroxyapatite thin films,” Mater. Sci. Eng. C., 27, 484–494 (2007).
A. Stoch, A. Brozek, and G. Kmita, et al., “Electrophoretic coating of hydroxyapatite on titanium implants,” J. Molecular Structure, 596, 191–200 (2001).
Y. Yanga, K. H. Kim, and J. L. Ong, “A review of calcium phosphate coatings produced using a sputtering process – an alternative to plasma spraying,” Biomaterials, 26, 327–337 (2005).
D. M. Liu, Q. Yang, and T. Troczynski, Sol-gel hydroxyapatite coatings on stainless steel substrates, Biomaterials, 23, 691–698 (2002).
Y. M. Lim, K. S.Hwang, and Y. J. Park, “Sol-gel derived functionally graded TiO2/HAP films on Ti–6Al–4V implants,” J. Sol-Gel Sci. Technol., 21, 23–128 (2001).
H. W. Kim, Y. H. Koh, L. H. Li, et al., “Hydroxyapatite coating on titanium substrate with titania buffer layer processed by sol-gel method,” Biomaterials, 25, 2533–2538 (2004).
R. Quan, D.Yang, X. Miao, et al., “Preparation of graded zirconia-hydroxyapatite composite bioceramic and its immunocompatibility in vitro,” J. Biomat. Appl., 22, 123–144 (2007).
R. J. Narayan, “Hydroxyapatite-diamond-like carbon nanocomposite films,” Mater. Sci. Eng. C., 25, 398–404 (2005).
T. Blaszczyk, B. Burnat, H. Scholl, et al., “The influence of NCD layers obtained by MW/RF PECVD method on surface properties of AISI 316L steel,” Eng. Biomat., 56–57, 31–34 (2006).
T. Blaszczyk, H. Scholl, A. Leniart, et al., “The influence of carbon layers on corrosion of Rex 734 and Panacea P558 alloys in 0.5 M NaCl and Tyrode’s solutions,” EUROCORR 2007 (9–13 September 2007, Freiburg); CD-ROM, paper 1077.
S. Mitura, A. Mitura, and P. Niedzielski, “Nanocrystalline Diamond Coatings,” Chaos, Solit. Frac., No. 9, 1054–1065 (1999).
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Published in Poroshkovaya Metallurgiya, Vol. 49, No. 7–8 (474), pp. 126–132, 2010.
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Pietrzyk, B., Gawronski, J. & Blaszczyk, T. Effect of carbon interlayer on protective properties of hydroxyapatite coating deposited on 316L stainless steel by sol-gel method. Powder Metall Met Ceram 49, 468–473 (2010). https://doi.org/10.1007/s11106-010-9260-2
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DOI: https://doi.org/10.1007/s11106-010-9260-2