The behavior of composite C–Cu–C film, which is deposited by dc magnetron sputtering and in which nanosized copper particles are located between two layers of amorphous carbon, is studied during annealing at 600°C in vacuum. The structural evolution is examined by transmission electron microscopy and electron diffraction. The structure of the composite film is found to be stable in annealing up to 15 h. The diffusion coalescence of copper particles is greatly restricted by the specific microstructure of carbon matrix.
Similar content being viewed by others
References
P. A. Chen, “Characteristics of copper-incorporated amorphous carbon film,” Thin Solid Films, 182, 261–263 (1989).
Y. Pauleau and F. Thièry, “Deposition and characterization of nanostructured metal/carbon composite films,” Surf. Coat. Technol., 180–181, 313–322 (2004).
C. C. Chen and F. C. N. Hong, “Structure and properties of diamond-like carbon nanocomposite films containing copper nanoparticles,” Appl. Surf. Sci., 242, 261–269 (2005).
T. Cabioc’h, A. Naudon, M. Jaouen, et al., “Co-sputtering C–Cu thin synthesis: microstructural study of copper precipitates encapsulated into a carbon matrix,” Phil Mag. B., 79, 501–516 (1999).
H. Hofsäss, H. Binder, T. Klumpp, et al., “Doping and growth of diamond-like carbon films by ion beam deposition,” Diamond Relat. Mater., 3, 137–142 (1993).
B. J. Jeon, H. Ko, J. Hyun, et al., “The effect of direct current bias on the characteristics of Cu/C:H composite thin films on polyethylene terephthalate film prepared by electron cyclotron resonance-metal organic chemical vapor deposition,” Thin Solid Films, 496, 395–401 (2006).
J. Musil, M. Louda, Z. Soukup, and M. Kubásek, “Relationship between mechanical properties and coefficient of friction of sputtered a-C/Cu composite thin films,” Diamond Relat. Mater., 17, 1905–1911 (2008).
A. A. Onoprienko, N. I. Danilenko, and I. A. Kossko, “Structure evolution on annealing of copper-doped carbon films,” Thin Solid Films, 515, 6672–6675 (2007).
A. A. Onoprienko and N. I. Danilenko, “Structural evolution in annealing of layered C–Cu films,” Powder Metall. Met. Ceram., 48, No. 1–2, 93–99 (2009).
A. A. Onoprienko, V. V. Artamonov, and I. B. Yanchuk, “Effect of magnetron discharge power on the resistivity and microstructure of carbon films,” Surf. Coat. Technol., 200, 4174–4178 (2006).
I. M. Lifshitz and V. V. Slyozov, “The kinetics of precipitation from supersaturated solid solutions,” J. Phys. Chem. Sol., 19, 35–50 (1961).
Ya. E. Geguzin, Yu. S. Kaganovsky, and V. V. Slyozov, “Determination of the surface heterodiffusion coefficient by the method of mass transfer,” J. Phys. Chem. Sol., 30, 1173–1178 (1969).
A. A. Onoprienko, V. V. Artamonov, and I. B. Yanchuk, “Effect of deposition and anneal temperature on the resistivity of magnetron sputtered carbon films,” Surf. Coat. Technol., 172, 189–193 (2003).
Author information
Authors and Affiliations
Corresponding author
Additional information
Translated from Poroshkovaya Metallurgiya, Vol. 49, No. 1–2 (471), pp. 66–71, 2010.
Rights and permissions
About this article
Cite this article
Onoprienko, A.A., Danilenko, N.I. Thermal stability of nanosized composite C–Cu films. Powder Metall Met Ceram 49, 50–54 (2010). https://doi.org/10.1007/s11106-010-9200-1
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11106-010-9200-1