Abstract
Potentiodynamic cycling is proposed to select conditions for the activation of zirconium-alloy electrodes of a nickel-hydride accumulator. The electrochemical characteristics of the electrodes are studied. It is shown that the full charge and discharge capacities are impossible in hydrogenation-dehydrogenation conditions that do not correspond to the polarization curves. The maximum discharge capacity under the same conditions is achieved for an electrode of 0.5 g while incomplete discharge capacity is observed for a sample of 0.1 g.
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O. A. Petrii, S. Ya. Vasina, and I. I. Korobov, “Electrochemistry of hydride-forming intermetallic compounds and alloys,” Usp. Khim., 65, No. 3, 196 (1996).
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Translated from Poroshkovaya Metallurgiya, Vol. 47, No. 7–8 (462), pp. 120–125, 2008.
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Solonin, Y.M., Lavrenko, V.A. & Galii, O.Z. Activation of the zirconium-alloy electrodes of nickel-metal hydride accumulator and determination of their hydrogen storage capacity. Powder Metall Met Ceram 47, 472–476 (2008). https://doi.org/10.1007/s11106-008-9045-z
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DOI: https://doi.org/10.1007/s11106-008-9045-z